一种具有螯合功能的重金属沉淀剂及其制备方法与应用

By preparing a heavy metal precipitant with chelating function, the problem of unsatisfactory treatment effect caused by different optimal pH values ​​of different heavy metal ions is solved, and efficient precipitation removal of low concentration heavy metal ions is achieved, which is suitable for industrial applications in electroplating, petrochemical and environmental protection fields.

CN119551789BActive Publication Date: 2026-07-17PAIRUI ELECTRIC APPLIANCE CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PAIRUI ELECTRIC APPLIANCE CO LTD
Filing Date
2024-10-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

When using existing chemical precipitation methods to treat heavy metal wastewater, the optimal pH value for the formation of hydroxides varies depending on the heavy metal ions, resulting in unsatisfactory treatment effects and secondary pollution.

Method used

Using polyacrylonitrile as raw material, a heavy metal precipitant with chelating function was prepared through amine oximeization, activation and nucleophilic substitution reactions. The activation reaction was introduced during the preparation process, which improved the reactivity and the exposure rate of functional groups, forming a highly active polyamine oxime intermediate, thereby enhancing the adsorption effect on low concentrations of heavy metal ions.

Benefits of technology

The prepared heavy metal precipitant has the characteristics of fast adsorption speed, large adsorption capacity, high strength and easy separation. It has a good precipitation and removal effect, especially for low concentration heavy metal ions. It is suitable for the treatment of heavy metal ion wastewater in electroplating, petrochemical and environmental protection fields and is easy to industrialize.

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Abstract

本发明属于重金属废水处理技术领域,具体涉及一种具有螯合功能的重金属沉淀剂及其制备方法与应用。该制备方法包括以下步骤:将聚丙烯腈加入羟胺类试剂中,调节pH值为6‑7,进行胺肟化反应,得到胺肟化的聚丙烯腈;将所述胺肟化的聚丙烯腈进行洗涤,然后加入到含活化剂的水溶液中,调节pH值为5‑8,进行活化反应,得到中间产物;将所述中间产物加入到含分散剂、表面活性剂及氯乙酸的水溶液中,调节pH值为6‑8,进行亲核取代反应,即得。该重金属沉淀剂的吸附容量大、吸附速度快,且对超低浓度的2价重金属离子具有优异的螯合功能,可以用于湿法冶金、环保等领域中贵重金属的提纯与回收,也可以用于铀、镓等稀有元素的分离与回收。
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