一种无隔膜电化学污水处理方法及装置

By using a membrane-free electrochemical method to form a dynamic anodic acidic zone and a cathode alkaline zone over a wide pH range, the problems of narrow pH range and iron sludge precipitation in Fenton oxidation and electro-Fenton methods are solved, enabling efficient catalyst reuse and degradation of recalcitrant organic pollutants.

CN119569186BActive Publication Date: 2026-07-17CHONGQING UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHONGQING UNIV
Filing Date
2024-12-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing Fenton oxidation and electro-Fenton methods for treating recalcitrant organic pollutants suffer from problems such as narrow pH range, low reaction efficiency due to electrode concentration polarization, and difficulty in treating iron sludge precipitation, requiring frequent addition of acids and alkalis to adjust the pH value.

Method used

Employing a diaphragm-free electrochemical method, this method couples the flow field and electric field to form an acidic anodic region, an alkaline cathodic region, and a metastable metal ion region. It utilizes the electrolysis of water to efficiently catalyze the degradation of organic pollutants over a wide pH range, avoiding the frequent pH adjustments and iron sludge precipitation treatment required in traditional methods.

Benefits of technology

It achieves highly efficient catalytic degradation over a wide pH range, reduces catalyst usage and treatment costs, improves reaction efficiency, avoids iron sludge formation, and extends membrane lifespan.

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Abstract

本发明提供了一种无隔膜电化学污水处理方法及装置,属于污水处理技术领域。将污水原液、氧化剂和催化剂混合,混合液同时平行于阳极和垂直于阴极流动,通过调控流场和电场使反应器中呈现动态稳定的阳极酸性区、阴极碱性区及金属离子亚稳态区,混合液平行流经阳极压缩酸性扩散层促进了阳极反应效率,垂直穿透多孔阴极的碱性扩散层将高价态的金属离子高效还原为低价态的金属离子、金属氧化物和纳米金属颗粒,再通过芬顿或类芬顿等催化反应产生了以羟基自由基以及高价态金属络合物来降解和矿化污水原液中的难降解有机污染物,反应前后无需投加大量酸碱调节污水原液pH值,活性物种产率高,并可通过对多孔阴极的间歇性反冲洗实现催化剂的循环利用。
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