一种PVDF / Ca-POM复合纤维膜、其制备方法及其在制备可穿戴柔性压电传感器中的应用

By using an electrochemical spinning method to form a double-network structure from PVDF and Ca-POM composite fiber membranes, the problem of insufficient mechanical properties of PVDF sensors is solved, and a high-performance wearable flexible piezoelectric sensor is realized.

CN119615497BActive Publication Date: 2026-07-17CHINA UNIV OF PETROLEUM (EAST CHINA)

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA UNIV OF PETROLEUM (EAST CHINA)
Filing Date
2024-12-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing PVDF materials have poor mechanical properties in wearable flexible piezoelectric sensors, making it difficult to simultaneously satisfy excellent piezoelectric and mechanical properties.

Method used

PVDF/Ca-POM composite fiber membranes were prepared by electrochemical spinning, utilizing the high flexibility and high aspect ratio of Ca-POM to form a double network structure, thereby improving the conformation of PVDF chains and the β phase content, and enhancing mechanical and piezoelectric properties.

Benefits of technology

The mechanical and piezoelectric properties of the PVDF/Ca-POM composite fiber membrane were improved, with a piezoelectric constant (d33) of 93.63 pm/V, a Young's modulus of 3.0 MPa, and an elongation of 88%, which is consistent with human skin and is suitable for wearable flexible piezoelectric sensors.

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Abstract

本发明公开了一种PVDF / Ca‑POM复合纤维膜、其制备方法及其在制备可穿戴柔性压电传感器中的应用,属于功能材料技术领域。所述复合纤维膜由PVDF和Ca‑POM经电化学纺丝制备而成。PVDF具有压电性,Ca‑POM具有高柔性和高长径比;PVDF与Ca‑POM之间能形成双网络,Ca‑POM的存在约束了PVDF链的运动,进一步提高了复合材料的力学性能;同时,Ca‑POM与PVDF之间的高偶极矩效应,能够改变PVDF链的构象,提高β相的相对含量,有效提高了复合材料的压电性能,保证了其作为可穿戴柔性压电传感器的灵敏性,从而在可穿戴柔性压电传感器领域存在重要应用前景。
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