一种三元正极材料的制备方法及所得三元正极材料、锂离子电池

By using nanoscale lithium salts as crystal nuclei in the synthesis of lithium nickel cobalt manganese oxide ternary cathode materials, a core-shell structured nano-intermediate is formed, which solves the problem of long lithium-ion diffusion paths and improves the electrochemical performance and cycle life of the material.

CN119695136BActive Publication Date: 2026-07-17安徽得壹能源科技有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
安徽得壹能源科技有限公司
Filing Date
2024-12-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing synthesis process of lithium nickel cobalt manganese oxide ternary cathode materials, the lithium ion diffusion path is relatively long, which leads to crystal defects, lattice distortion and lattice stress, affecting electrochemical performance.

Method used

Using nanoscale non-water-soluble or slightly water-soluble lithium salts as crystal nuclei, a core-shell structured nano-intermediate is formed through a co-precipitation reaction, shortening the lithium-ion diffusion path, and then calcined with a lithium source to prepare ternary cathode materials.

Benefits of technology

The lattice stress and lattice defects of the ternary cathode material were improved, thereby enhancing the material's cycle stability and electrochemical performance. The capacity retention rate was over 90% after 50 cycles at 0.5C/1C and over 85% after 100 cycles.

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Abstract

本发明公开了一种三元正极材料的制备方法及所得三元正极材料、锂离子电池,属于锂离子电池电极材料技术领域。本发明所述的制备方法如下:将纳米级锂盐悬浊液通入到三元前驱体母液中混合均匀,得到混合分散液;向所述混合分散液中分别通入镍盐、钴盐和锰盐溶液,调节pH值以发生共沉淀反应,得到核壳纳米中间体;进行所述核壳纳米中间体的生长和陈化,得到预锂前驱体;将所述预锂前驱体与锂源混合,在含氧气氛下煅烧后即得三元正极材料。本发明的共沉淀过程以纳米级非水溶性或微水溶性锂盐作为晶核,该方法能够有效缩短在三元正极材料生产过程中锂离子扩散路径长度,使得制备得到的三元正极材料在应用于锂离子电池时具有优异的循环稳定性。
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