Natural graphite, electrochemical device and preparation method of natural graphite

By doping P and/or N elements in natural graphite and adopting gradient distribution technology, combining high-frequency thermal shaping and cold quenching treatment preparation methods, the problem of poor circulation and storage performance of natural graphite in lithium-ion batteries is solved, and higher battery performance and service life are achieved.

CN119735204AActive Publication Date: 2025-04-01ENVISION DYNAMICS TECH (JIANGSU) CO LTD +1
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Patent Information

Application Number
CN202411962908.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-27
Publication Date
2025-04-01
Estimated Expiration
2044-12-27

AI Technical Summary

Technical Problem

As a negative electrode material for lithium-ion batteries, natural graphite has poor circulation and storage performance, mainly due to its abundant pores and functional groups, which are prone to side reactions with the electrolyte, and lattice expansion and particle peeling are prone to occur during charging and discharging.

Method used

Through the gradient distribution of doping elements P and/or N in the natural graphite core, a hard inside and soft outside are formed to reduce side reactions and expansion problems. At the same time, high-frequency thermal shaping and cold quenching treatment are used during the preparation process to optimize the structure and performance of the material.

Benefits of technology

It significantly improves the circulation and storage performance of natural graphite, improves the charging and discharge capacity and rate performance of the battery, reduces the expansion and side reaction of the material, and extends the service life of the battery.

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Abstract

The invention provides natural graphite, an electrochemical device and a preparation method of the natural graphite, and belongs to the technical field of secondary batteries, the natural graphite comprises a natural graphite nuclear body, the natural graphite nuclear body is doped with a doping element, and the doping element comprises P or N; the gradient concentration ratio of the doping element in the natural graphite nuclear body is 2.4 to 3.8; the gradient concentration ratio is the mass ratio of a doping element in a first gradient region to a doping element in a second gradient region in the natural graphite nuclear body. The natural graphite has the advantages of high capacity, low expansion and high rate performance, and compared with the existing natural graphite material, the natural graphite can effectively improve the storage and cycle performance of the assembled battery.
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