一种二维碳化钨纳米片负载非贵金属催化剂及制备和应用

A simplified preparation method was used to prepare a two-dimensional tungsten carbide nanosheet-supported non-precious metal catalyst, which solved the problems of complex preparation and high cost in the existing technology. It achieved high efficiency in water electrolysis catalysis and is easy to mass-produce. The catalyst exhibited excellent electrochemical oxygen evolution performance in water electrolysis.

CN119736662BActive Publication Date: 2026-07-17SHANGHAI JIAOTONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANGHAI JIAOTONG UNIV
Filing Date
2024-12-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for preparing non-precious metal catalysts supported on two-dimensional tungsten carbide nanosheets are complex, costly, and have low yields, and their durability and catalytic performance in the water electrolysis process need to be improved.

Method used

Two-dimensional tungsten carbide nanosheets were prepared by reacting ethanol and hydrogen peroxide aqueous solution. The solid powder was obtained by mechanical stirring and heating evaporation, and then calcined in a tube furnace and reduced with non-precious metal salt and sodium borohydride to prepare a non-precious metal catalyst supported on two-dimensional tungsten carbide nanosheets.

Benefits of technology

The prepared catalyst exhibits excellent electrochemical oxygen evolution performance in water electrolysis, with low overpotential and large specific surface area, providing more active reaction sites. The method is simple, easy to prepare in large quantities, and low in cost.

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Abstract

本发明公开了一种二维碳化钨纳米片负载非贵金属催化剂的制备方法及电解水应用。本发明首次通过熔融盐法制备了二维碳化钨纳米片。随后,通过湿化学还原法在二维碳化钨纳米片上负载了各种不同的非贵金属合金,制备了一系列二维碳化钨纳米片负载的非贵金属催化剂。该方法具有高的普适性,操作简便,成本低廉,制备的二维碳化钨纳米片负载的非贵金属催化剂在电催化析氧领域展现了超高催化活性,具备替代商业氧化钌催化剂的潜力。
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