一种适配高压实型磷酸铁锂的大单晶磷酸铁及其制备方法

By preparing large single-crystal lithium iron phosphate using fertilizer acid and controlling the dropping and heating regime of the oxidant, the problems of low efficiency, high energy consumption, and environmental pollution in improving the compaction density of lithium iron phosphate in existing technologies have been solved, achieving efficient and low-cost lithium iron phosphate production.

CN119776967BActive Publication Date: 2026-07-17GUIZHOU PHOSPHATING NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUIZHOU PHOSPHATING NEW MATERIAL TECH CO LTD
Filing Date
2024-12-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for increasing the compaction density of lithium iron phosphate suffer from low production efficiency, high energy consumption, large equipment investment, significant environmental pollution, and high post-processing costs, making them unsuitable for large-scale production.

Method used

By using fertilizer acid as the phosphorus source and controlling the dropping ratio of the oxidant, the stirring regime, and the temperature rise regime of the aging process, large single crystal iron phosphate is prepared, avoiding the use of additives and template agents, simplifying the process, and reducing production costs and environmental pollution.

Benefits of technology

The preparation of high-quality large single-crystal iron phosphate has been achieved, which improves electrochemical performance, reduces production costs, simplifies the process, and increases production efficiency, making it suitable for large-scale production.

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Abstract

本发明涉及锂电池正极材料制备技术领域,具体为一种适配高压实型磷酸铁锂的大单晶磷酸铁及其制备方法,包括如下步骤:S1、化肥酸稀释后,加入除杂剂、絮凝剂,过滤,得到净化化肥酸溶液;净化化肥酸溶液与磷酸复配得溶铁液,溶铁液中磷酸的质量浓度为10~45%;S2、将铁源加入溶铁液中,升温,溶解,过滤,得到磷铁溶液;S3、磷铁溶液在一定温度下,加入氧化剂Ⅰ进行氧化反应,得到反应溶液;S4、反应溶液中加入氧化剂Ⅱ,在一定温度下进行保温老化,得老化溶液;S5、老化溶液经过滤,洗涤,干燥,煅烧,得到大单晶磷酸铁。可以解决目前适配高压实型磷酸铁锂的磷酸铁,生产效率低、能耗高、设备投资大,环境污染大,后处理成本高的问题。
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