一种增强型聚苯并咪唑离子溶剂化复合膜及其制备和应用

By preparing an enhanced polybenzimidazole ion-solventized composite membrane, the problem of low OH- conductivity in traditional alkaline water electrolysis for hydrogen production was solved, achieving a highly efficient water electrolysis hydrogen production effect, reducing energy consumption and improving conductivity and current density.

CN119823380BActive Publication Date: 2026-07-17ZHEJIANG UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHEJIANG UNIV OF TECH
Filing Date
2024-12-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing alkaline water electrolysis hydrogen production technologies, traditional membranes have low OH- conductivity, resulting in low efficiency and high energy consumption in water electrolysis hydrogen production. It is necessary to develop exchange membranes with high OH- conductivity to improve the efficiency of water electrolysis hydrogen production and reduce energy consumption.

Method used

An enhanced polybenzimidazole ion-solventized composite membrane was prepared by polycondensation reaction of polyphosphoric acid, adding inorganic oxide nanoparticles, and combining with a mesh support material to prepare a composite membrane with high conductivity and low surface resistance.

Benefits of technology

It can operate stably in a high-concentration alkaline environment for a long time, with the membrane surface resistance reduced to 0.035Ω·cm2, the current density reaching more than 8000mA·cm-2, the conductivity reaching up to 884mS·cm-1, the cold start response speed fast, and the electrolytic cell ohmic resistance low.

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Abstract

本发明公开了一种增强型聚苯并咪唑离子溶剂化复合膜及其制备和应用。增强型聚苯并咪唑离子溶剂化复合膜的制备方法包括:(1)在多聚磷酸中,芳香四胺单体和二羧酸单体进行缩聚反应,反应至得到黏稠的聚苯并咪唑溶液,加入磷酸溶液分散的无机氧化物纳米颗粒,搅拌均匀脱气后,得到铸膜液;(2)将铸膜液直接浇注于玻璃板上,刮膜后将隔网作为支撑材料平铺在膜上,再倒入铸膜液进行刮膜,接着进行水解得到凝胶复合膜;将凝胶复合膜依次在碳酸盐水溶液、水、碱溶液中充分浸泡,得到增强型聚苯并咪唑离子溶剂化复合膜。本发明提供了所述复合膜在碱性电解水中的应用。本发明的复合膜具有膜面电阻低、电化学性能优异等特点。
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