一种现场可视化定量检测烯啶虫胺的MOFs基混合基质膜及其制备方法与应用

By dispersing MOF crystals in a polymer matrix to prepare a mixed matrix membrane, the problem of uneven dispersion of MOF crystals in solution is solved, enabling on-site quantitative detection by a portable fluorescence sensor and improving detection sensitivity and recyclability.

CN119842104BActive Publication Date: 2026-07-17SHANDONG UNIV OF POLITICAL SCI & LAW

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG UNIV OF POLITICAL SCI & LAW
Filing Date
2025-01-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, the poor solubility of MOF crystals leads to uneven dispersion in analyte solutions, affecting sensitivity and accuracy. Furthermore, they are difficult to recover, limiting the sensitivity and recyclability of fluorescence detection and making it difficult to achieve portable, real-time on-site detection.

Method used

MOFs crystals are uniformly dispersed in a polymer matrix to prepare MOFs-based hybrid matrix membranes. Combining the flexibility and mechanical stability of the polymer, on-site visual quantitative detection is performed with the assistance of a smartphone.

Benefits of technology

This invention achieves portability, ease of operation, fast detection speed, and convenient recovery of MOFs-based hybrid matrix membranes, enabling on-site visual quantitative detection of acetamiprid, and improving the sensitivity and accuracy of detection.

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Abstract

本发明属于材料和检测领域,提供了一种现场可视化定量检测烯啶虫胺的MOFs基混合基质膜及其制备方法与应用。将稳定的发光Zn‑MOF(1)材料掺入聚甲基丙烯酸甲酯(PMMA)粘合剂中,成功制备出混合基质膜(1@PMMA)。该混合基质膜兼具Zn‑MOF(1)的优异发光特性和PMMA的柔韧性与良好加工性,对烯啶虫胺(NTP)表现出高灵敏度、强抗干扰性、可回收性以及可视化检测能力。同时将上述1@PMMA混合基质膜与智能手机相结合,构建了一种便携式智能手机辅助荧光传感平台,该平台能够实现对NTP的现场可视化定量检测,极大地提升了食品安全监测的便捷性和准确性。
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