一种锰金属有机框架材料的制备方法及其在水系锌电池中的应用
By controlling the molar ratio of pyromellitic acid to manganese acetate tetrahydrate and the order of addition, a uniform flower-shaped manganese metal-organic framework material was prepared, which solved the problem of uneven morphology of MnMOFs materials and improved the electrochemical performance of aqueous zinc-ion batteries.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- YANGZHOU UNIV
- Filing Date
- 2025-01-15
- Publication Date
- 2026-07-17
AI Technical Summary
Existing MnMOFs materials suffer from problems such as uneven morphology and large size in aqueous zinc-ion batteries, which affect their electrochemical performance.
By controlling the molar ratio of pyromellitic acid to manganese acetate tetrahydrate to 1:(1.5-3.2), and with the coordination of surfactant and raw material molar ratio, manganese metal-organic framework materials were prepared by using a specific dropwise order to form a uniform flower-shaped morphology.
The prepared manganese metal-organic framework material exhibits a high specific surface area, which promotes the insertion and extraction of Zn2+, improves the conductivity, ion conduction performance and structural stability of aqueous zinc-ion batteries, and has excellent specific capacity and longer cycle life.
Smart Images
Figure CN119875136B_ABST