一种咔唑基双查尔酮及其制备方法和应用

By preparing carbazole-based bischalcone photoinitiator, the migration and toxicity problems of existing photoinitiators were solved, enabling rapid photoinitiation and deep curing, thus expanding its application in the biomedical field.

CN119912385BActive Publication Date: 2026-07-17GUIZHOU EDUCATION UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUIZHOU EDUCATION UNIV
Filing Date
2025-01-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing photoinitiators such as camphorquinone (CQ) and ITX have migration problems and certain reproductive toxicity, which limits their application in the biomedical field. The development of single-component, low-toxicity photoinitiators has not yet been effectively solved.

Method used

A carbazolyl bischalcone photoinitiator is provided, prepared by the Claisen-Schmidt reaction, and used as a single-component photoinitiator or in combination with a hydrogen donor to initiate the polymerization of acrylate monomers, and photocured using an LED light source.

Benefits of technology

It achieves rapid photoinitiation speed and high double bond conversion rate, enabling it to be used in deep curing systems to prepare thicker polymer materials. It is suitable for the polymerization of various acrylate monomers, including fluorinated monomers, expanding its application prospects in the biomedical field.

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Abstract

本发明提供了一种咔唑基双查尔酮及其制备方法和应用,属于光引发剂技术领域。本发明提供的咔唑基双查尔酮的化学结构式如式Ⅰ所示;所述式Ⅰ中,R为‑H、‑SMe、‑OMe、NMe2、NEt2、CF3或‑N(Ph)2。本发明控制咔唑基双查尔酮的具体结构,使得其在作为光引发剂引发丙烯酸酯类单体发生聚合反应时,光引发速度快、双键转化率高且能够用于深度固化体系。
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