一种基于香榧蒲生物质衍生碳的锂氯电池材料的制备工艺

By synthesizing ACOPs and Ni-NC composite materials through a specific preparation process, the problem of uneven pore distribution in lithium-chlorine batteries was solved, achieving efficient transport and redox of LiCl and Cl2, and improving the reaction efficiency and cycle life of lithium-chlorine batteries.

CN119978321BActive Publication Date: 2026-07-17ZHEJIANG FORESTRY UNIVERSITY +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHEJIANG FORESTRY UNIVERSITY
Filing Date
2024-12-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The uneven and insufficient pore distribution in lithium-chlorine batteries leads to slow kinetics between LiCl and Cl2, resulting in residual LiCl solids that block the pores and interfere with the redox reaction. Furthermore, excessive loss of Cl2 limits the efficiency of the redox reaction.

Method used

A lithium-chlorine battery material preparation process based on carbon derived from Torreya grandis biomass was adopted. By synthesizing ACOPs and combining them with Ni-NC, a composite material with regularly arranged open channels and alkynyl functional groups was formed, which promoted the transport of Cl- and Li+ and alleviated the volume expansion of discharge products.

Benefits of technology

Rapid redox kinetics of LiCl were achieved, improving the battery's reaction efficiency and cycle life, and ensuring the stability of the battery structure and efficient energy storage.

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Abstract

本发明提出了一种基于香榧蒲生物质衍生碳的锂氯电池材料的制备工艺,通过将超稳定的共价有机聚合物(ACOPs)与Ni单原子纳米颗粒修饰的香榧蒲生物质衍生碳纳米材料复合,成功地制备了一种高效的ACOPs基正极复合材料。ACOPs的炔基官能(‑C≡C‑)团周期性地分布在纳米孔中,表现出优异的氯气吸附能力。ACOPs具有规则排列的开放通道,有利于Cl‑和Li+的传输,从而实现LiCl的快速氧化还原动力学转化。此外,复合物中的共价网络结构可以缓解放电产物产生的体积膨胀,促进电池长寿命循环。
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