A thiol-modified nickel MOF nanosheet array material, a preparation method and application thereof

By using thiol-modified nickel MOF nanosheet arrays, the conductivity and stability issues of nickel MOF nanosheet arrays in electrocatalysis were solved, enabling efficient catalysis of the oxidation of 1,4-butanediol and PBS plastic hydrolysis products to generate high-value-added succinate.

CN120006344BActive Publication Date: 2026-07-21TONGJI UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TONGJI UNIV
Filing Date
2025-01-10
Publication Date
2026-07-21

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Abstract

The application relates to the technical field of catalysts, in particular to a mercaptan-modified nickel MOF nanosheet array material and a preparation method and application thereof. The preparation method is as follows: nickel salt, terephthalic acid, 1,4-benzenedimercaptan and a solvent are mixed to obtain a reaction solution; the foamed nickel is soaked in the reaction solution to perform a hydrothermal reaction; and after the reaction is completed, a nickel MOF material loaded on the foamed nickel, that is, the mercaptan-modified nickel MOF nanosheet array material, is obtained. Compared with the prior art, the catalytic activity of the MOF nanosheet array material is improved, and then the catalytic efficiency and the catalytic stability are improved, so that the 1,4-butanediol and the PBS plastic hydrolysis product can be effectively catalyzed and oxidized.
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