电池内局部电解液电导率和浓度的检测方法及其应用

By setting microelectrodes inside lithium-ion batteries and using impedance spectroscopy detection, the problem of inefficient detection of local electrolyte concentration in existing technologies has been solved, enabling non-destructive and low-cost monitoring and aging analysis of electrolyte distribution.

CN120064387BActive Publication Date: 2026-07-17XIAMEN UNIV +2

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XIAMEN UNIV
Filing Date
2025-02-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for efficiently and non-destructively detecting the concentration of local electrolytes inside lithium-ion batteries. Furthermore, traditional methods are costly and require complex equipment, making them unsuitable for the daily monitoring needs of large-scale batteries.

Method used

An impedance spectroscopy detection method combining microelectrodes and transmission line models is adopted. By placing microelectrodes inside the battery, applying voltage perturbation and measuring impedance or resistance, the conductivity and concentration of the local electrolyte are obtained by fitting a standard curve.

Benefits of technology

It enables non-destructive, simple, and efficient detection of local electrolyte concentration and distribution uniformity inside batteries, and can monitor electrolyte change trends during battery aging, thus reducing detection costs.

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Abstract

本发明涉及电池技术领域,公开了电池内局部电解液浓度及电导率的检测方法,包括:提供测试电池,测试电池包括电池本体和位于电池本体内待检部位的微电极,电池本体的电极与微电极的体积比至少为100:1;每个微电极表面具有能够使电解液进入的孔隙结构;采用阻抗谱检测方法测试进入到孔隙结构内的电解液浓度及电导率,或者,采用单点频率测试法测试进入到孔隙结构内的电解液浓度及电导率。该方法能对局部电解液进行检测,了解电池内部电解液的均匀性也可以了解电池电解液电导率的变化;能够用于了解电池老化过程电解液阻抗变化趋势以及锂盐消耗情况。该方法不存在电池的拆解,测试过程简单高效。
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