生活垃圾焚烧飞灰中氯离子洗脱协同二噁英降解的方法

By combining landfill leachate concentrate washing with low-temperature pyrolysis, the dependence of low-temperature pyrolysis technology on an inert atmosphere has been solved, achieving efficient degradation and resource utilization of dioxins in municipal solid waste incineration fly ash.

CN120094934BActive Publication Date: 2026-07-17GUANGDONG GUANGYE INVESTMENT GRP CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUANGDONG GUANGYE INVESTMENT GRP CO LTD
Filing Date
2025-04-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing low-temperature pyrolysis technology requires a strictly inert atmosphere to prevent oxygen leakage when degrading dioxins in fly ash from municipal solid waste incineration, resulting in high energy consumption and low efficiency, making it difficult to promote.

Method used

The fly ash from municipal solid waste incineration is washed, filtered, and subjected to three-stage countercurrent water washing using leachate concentrate. After adsorbing organic matter, it undergoes low-temperature pyrolysis without the introduction of nitrogen gas. The organic matter in the leachate consumes oxygen, and the oxygen concentration in the low-temperature pyrolysis atmosphere is controlled to be below 1%.

Benefits of technology

It achieves efficient degradation of dioxins without relying on a nitrogen atmosphere, saving resources and simplifying the process. Furthermore, chloride ions and metals in fly ash can be utilized as resources, with a degradation efficiency of 99.4-99.5%.

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Abstract

本发明涉及生活垃圾焚烧飞灰处置技术领域,公开生活垃圾焚烧飞灰中氯离子洗脱协同二噁英降解的方法,包括:使用垃圾渗滤浓缩液对生活垃圾焚烧飞灰进行洗涤、压滤,使垃圾渗滤浓缩液中有机物吸附在生活垃圾焚烧飞灰上;对生活垃圾焚烧飞灰进行三级逆流水洗,压滤;在不通氮情况下对生活垃圾焚烧飞灰进行烘干及低温热解,以降解二噁英;吸附在生活垃圾焚烧飞灰上的渗滤液中的有机物化学需氧量不低于500mg / L,能够消耗低温热解气氛中的氧气,使低温热解气氛中的氧气体积浓度不超过1%。本发明可有效洗脱生活垃圾焚烧飞灰中的氯离子并在不依赖氮气控氧情况下降解生活垃圾焚烧飞灰中的二噁英,对生活垃圾焚烧飞灰具有很好的脱氯解毒效果。
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