Method, device and storage medium for determining percolation properties of carbon black networks

CN120105846BActive Publication Date: 2026-10-23ELECTRIC POWER RES INST CHINA SOUTHERN POWER GRID CO LTD +1
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Patent Information

Application Number
CN202510196866.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-02-21
Publication Date
2026-10-23
Estimated Expiration
2045-02-21

AI Technical Summary

Technical Problem

[0004]传统技术中,逾渗模型的构建通常是利用元胞自动机方法研究二维平面规则晶格上的逾渗相变,这种建模思路相对简便,但在构建符合导电相结合特性的三维逾渗模型时,确定逾渗性能的准确率较低

Benefits of technology

[0041]上述炭黑网络的逾渗性能确定方法、装置、计算机设备、计算机可读存储介质和计算机程序产品,根据模型参数,在三维空间中构建炭黑网络的逾渗模型,其中,逾渗模型用于模拟炭黑网络中各个炭黑粒子在三维空间中的分布情况;向逾渗模型中逐步插入新的炭黑粒子,得到更新后逾渗模型;在更新后逾渗模型包括的多个炭黑粒子之间搜索出目标导电路径,其中,目标导电路径为贯穿三维空间中第一表面和第二表面的导电路径,第一表面与第二表面在三维空间中的高度差值大于差值阈值;更新模型参数,并返回至基于模型参数,在三维空间中构建炭黑网络的逾渗模型的步骤,直至满足循环结束条件;根据在多次循环中分别搜索到目标导电路径的概率,确定炭黑网络的逾渗性能。通过逐步插入炭黑粒子并动态更新逾渗模型,结合目标导电路径的搜索和逾渗概率的统计,能够在三维空间中精准模拟炭黑粒子的分布和连接特性,构建高精度的逾渗模型,从而显著提高逾渗性能的确定准确性,从而为高压电缆半导电屏蔽料配方优化提供科学依据,进一步提升材料的导电性能、加工性能及电缆整体性能。

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Abstract

The application relates to a percolation performance determination method, device and equipment of a carbon black network and a storage medium. The method comprises the following steps: constructing a percolation model of the carbon black network in a three-dimensional space based on model parameters; gradually inserting new carbon black particles into the percolation model to obtain an updated percolation model; searching for a target conductive path among a plurality of carbon black particles included in the updated percolation model; the target conductive path is a conductive path penetrating through a first surface and a second surface in the three-dimensional space; updating the model parameters and returning to the step of constructing the percolation model of the carbon black network in the three-dimensional space based on the model parameters until a loop end condition is met; and determining the percolation performance of the carbon black network based on the probabilities of searching for the target conductive path in multiple loops. The method can improve the accuracy of determining the percolation performance.
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Description

Technical Field

[0001] This application relates to the field of materials modeling technology, and in particular to a method, apparatus, computer device, computer-readable storage medium, and computer program product for determining the percolation properties of a carbon black network. Background Technology

[0002] Semiconducting shielding material is a crucial and decisive material in high-voltage cables, mainly composed of a matrix resin, conductive filler, crosslinking agent, antioxidant, and other processing aids, obtained through melt blending. The conductive filler is a key component of the semiconducting shielding material, determining its critical electrical, mechanical, thermal, processability, and surface finish properties. Conductive carbon black, due to its excellent electrical properties and low cost, has become the primary choice for conductive filler in the production of high-voltage cable semiconducting shielding materials. The properties of conductive carbon black are crucial in determining the performance of the semiconducting shielding material. In high-voltage cable shielding materials, the use of conductive carbon black can improve the material's conductivity, enhance the shielding effect, and improve the overall performance of the cable. Studies have shown that the distribution and concentration of carbon black have a significant impact on the electrical properties of the shielding material.

[0003] Percolation models for conductive carbon black are crucial for optimizing material formulations and improving product performance. Percolation theory is an important tool for studying the electrical conductivity of materials, allowing us to understand how the distribution and bonding of conductive particles in the matrix affect the overall conductivity of the material. The formation mechanism of carbon black percolation is complex and influenced by various factors, including particle size distribution, content ratio, and matrix material properties. Therefore, by constructing percolation models, we can better simulate the bonding patterns of carbon black at different particle sizes and contents, and predict its percolation performance.

[0004] In traditional techniques, percolation models are typically constructed using cellular automata methods to study percolation phase transitions on two-dimensional planar regular lattices. This modeling approach is relatively simple, but when constructing a three-dimensional percolation model that conforms to the conductivity binding characteristics, the accuracy of determining percolation performance is low. Summary of the Invention

[0005] Therefore, it is necessary to provide a method, apparatus, computer equipment, computer-readable storage medium, and computer program product for determining the percolation performance of carbon black networks, which can improve the accuracy of determining percolation performance, in response to the above-mentioned technical problems.

[0006] In a first aspect, this application provides a method for determining the percolation properties of a carbon black network, comprising:

[0007] Based on model parameters, a percolation model of a carbon black network is constructed in three-dimensional space; the percolation model is used to simulate the distribution of each carbon black particle in the carbon black network in the three-dimensional space.

[0008] New carbon black particles are gradually inserted into the percolation model to obtain an updated percolation model.

[0009] The target conductive path is searched among the multiple carbon black particles included in the updated percolation model; the target conductive path is a conductive path that runs through the first surface and the second surface in the three-dimensional space; the height difference between the first surface and the second surface in the three-dimensional space is greater than the difference threshold.

[0010] Update the model parameters and return to the step of constructing a percolation model of a carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met;

[0011] The percolation performance of the carbon black network is determined based on the probability of finding the target conductive path in multiple iterations.

[0012] In one embodiment, the stepwise insertion of new carbon black particles into the percolation model to obtain an updated percolation model includes:

[0013] New carbon black particles are gradually inserted into the percolation model;

[0014] Based on the distance between the new carbon black particles and the original carbon black particles in the percolation model, the conductive group to which the new carbon black particles belong in the percolation model is determined to obtain the updated conductive group; the conductive group is a collection of multiple carbon black particles that form a conductive path.

[0015] Based on the updated conductive group, the updated percolation model is obtained.

[0016] In one embodiment, determining the conductive group to which the new carbon black particles belong in the percolation model based on the distance between the new carbon black particles and the existing carbon black particles in the percolation model includes:

[0017] Based on the distance between the new carbon black particles and the original carbon black particles in the percolation model, target particles whose distance is less than a preset limit distance are determined from the original carbon black particles.

[0018] If each of the target particles belongs to the same conductive group, then the new carbon black particles are determined to belong to the same conductive group.

[0019] If each of the target particles belongs to at least one different conductive group, then the different conductive groups are merged into a new conductive group, and the new carbon black particles are determined to belong to the new conductive group.

[0020] In one embodiment, the step of searching for the target conductive path among the multiple carbon black particles included in the updated percolation model includes:

[0021] The maximum conductive group is searched among the conductive groups included in the updated percolation model; the maximum conductive group is the conductive group containing the largest number of carbon black particles.

[0022] In the case where the largest conductive group penetrates the first and second surfaces in the three-dimensional space, the target conductive path is determined from the conductive paths contained in the largest conductive group.

[0023] In one embodiment, determining the percolation performance of the carbon black network based on the probability of finding the target conductive path in multiple loops includes:

[0024] If the probability of finding the target conductive path is greater than or equal to a probability threshold, the updated percolation model is determined to have reached a percolation state; the percolation state is the state in which the target conductive path exists in the updated percolation model.

[0025] The percolation threshold of the carbon black network is determined based on the average carbon black particle content corresponding to the percolation state when the updated percolation model reaches the percolation state in the multiple iterations; the percolation threshold is used to characterize the ease with which the carbon black network reaches the percolation state.

[0026] In one embodiment, constructing a percolation model of the carbon black network in three-dimensional space based on model parameters includes:

[0027] Obtain the preset carbon black particle diameter, preset carbon black particle set quantity, and preset carbon black particle quantity contained in each carbon black particle set from the model parameters.

[0028] During the construction of the current carbon black particle set, according to the preset particle distance, several new carbon black particles are generated around the original carbon black particles in the current carbon black particle set; the diameter of the several new carbon black particles conforms to the preset carbon black particle diameter.

[0029] When the several new carbon black particles are located in the three-dimensional space and do not overlap with other carbon black particles in the current carbon black particle set, the several new carbon black particles are added to the current carbon black particle set, and the process returns to the step of generating several new carbon black particles around the original carbon black particles in the current carbon black particle set according to the preset particle distance, until the number of carbon black particles contained in the current carbon black particle set meets the preset number of carbon black particles;

[0030] Continue to construct the next set of carbon black particles, take the next set of carbon black particles as the current set of carbon black particles, and return to the step of generating a number of new carbon black particles around the original carbon black particles in the current set of carbon black particles according to the preset particle distance during the construction of the current set of carbon black particles, until multiple sets of carbon black particles that meet the preset number of carbon black particles are generated.

[0031] Based on the multiple sets of carbon black particles, a percolation model of the carbon black network is constructed in the three-dimensional space.

[0032] Secondly, this application also provides an apparatus for determining the percolation properties of a carbon black network, comprising:

[0033] A construction module is used to construct a percolation model of a carbon black network in three-dimensional space based on model parameters; the percolation model is used to simulate the distribution of each carbon black particle in the carbon black network in the three-dimensional space.

[0034] The update module is used to gradually insert new carbon black particles into the percolation model to obtain an updated percolation model.

[0035] The search module is used to search for target conductive paths among multiple carbon black particles included in the updated percolation model, and record the percolation probability of finding the target conductive path; the target conductive path is a conductive path that runs through the first surface and the second surface in the three-dimensional space; the height difference between the first surface and the second surface in the three-dimensional space is greater than the difference threshold.

[0036] The update module is also used to update the model parameters and return to the step of constructing a percolation model of a carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met.

[0037] A determination module is used to determine the percolation performance of the carbon black network based on the percolation probabilities recorded in multiple cycles.

[0038] Thirdly, this application also provides a computer device, including a memory and a processor, wherein the memory stores a computer program, and the processor executes the computer program to implement the steps of the above-described method.

[0039] Fourthly, this application also provides a computer-readable storage medium having a computer program stored thereon, which, when executed by a processor, implements the steps of the above-described method.

[0040] Fifthly, this application also provides a computer program product, including a computer program that, when executed by a processor, implements the steps of the above-described method.

[0041] The aforementioned method, apparatus, computer equipment, computer-readable storage medium, and computer program product for determining the percolation performance of a carbon black network construct a percolation model of the carbon black network in three-dimensional space based on model parameters. The percolation model simulates the distribution of individual carbon black particles in the carbon black network within the three-dimensional space. New carbon black particles are progressively inserted into the percolation model to obtain an updated percolation model. A target conductive path is searched among the multiple carbon black particles included in the updated percolation model. This target conductive path is a conductive path that traverses a first surface and a second surface in three-dimensional space, and the height difference between the first surface and the second surface in three-dimensional space is greater than a difference threshold. The model parameters are updated, and the process returns to the step of constructing the percolation model of the carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met. The percolation performance of the carbon black network is determined based on the probability of finding the target conductive path in each of the multiple loops. By progressively inserting carbon black particles and dynamically updating the percolation model, combined with the search for the target conductive path and the statistics of percolation probability, the distribution and connection characteristics of carbon black particles can be accurately simulated in three-dimensional space, constructing a high-precision percolation model. This significantly improves the accuracy of percolation performance determination, providing a scientific basis for optimizing the formulation of semi-conductive shielding materials for high-voltage cables, and further enhancing the conductivity, processing performance, and overall cable performance of the material. Attached Figure Description

[0042] To more clearly illustrate the technical solutions in the embodiments of this application or related technologies, the drawings used in the description of the embodiments of this application or related technologies will be briefly introduced below. Obviously, the drawings described below are only some embodiments of this application. For those skilled in the art, other related drawings can be obtained based on these drawings without creative effort.

[0043] Figure 1 This is an application environment diagram of a method for determining the percolation performance of a carbon black network in one embodiment.

[0044] Figure 2 This is a flowchart illustrating a method for determining the percolation performance of a carbon black network in one embodiment.

[0045] Figure 3 This is a schematic diagram of a conductive path in one embodiment;

[0046] Figure 4 This is a schematic diagram illustrating the changes in the percolation threshold and percolation probability of a percolation model in one embodiment;

[0047] Figure 5 An apparatus for determining the percolation properties of a carbon black network in one embodiment;

[0048] Figure 6This is an internal structural diagram of a computer device in one embodiment. Detailed Implementation

[0049] To make the objectives, technical solutions, and advantages of this application clearer, the following detailed description is provided in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative and not intended to limit the scope of this application.

[0050] The method for determining the percolation performance of carbon black networks provided in this application embodiment can be applied to, for example... Figure 1 In the application environment shown, terminal 102 communicates with server 104 via a network. A data storage system can store the data that server 104 needs to process. The data storage system can be integrated onto server 104 or placed on a cloud or other network server. Terminal 102 constructs a percolation model of the carbon black network in three-dimensional space based on model parameters. The percolation model simulates the distribution of individual carbon black particles in the carbon black network in three-dimensional space. Terminal 102 progressively inserts new carbon black particles into the percolation model to obtain an updated percolation model. Terminal 102 searches for target conductive paths among the multiple carbon black particles included in the updated percolation model. The target conductive path is a conductive path that runs through the first and second surfaces in three-dimensional space. The height difference between the first and second surfaces in three-dimensional space is greater than a difference threshold. Terminal 102 updates the model parameters and returns to the step of constructing the percolation model of the carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met. Terminal 102 determines the percolation performance of the carbon black network based on the probability of finding the target conductive path in multiple loops. The terminal 102 can be, but is not limited to, various personal computers, laptops, smartphones, tablets, IoT devices, and portable wearable devices. IoT devices can include smart speakers, smart TVs, smart air conditioners, smart in-vehicle systems, and projection devices. Portable wearable devices can include smartwatches, smart bracelets, and head-mounted displays. Head-mounted displays can be virtual reality (VR) devices, augmented reality (AR) devices, and smart glasses. The server 104 can be a standalone physical server, a server cluster or distributed system composed of multiple physical servers, or a cloud server providing cloud computing services.

[0051] In one exemplary embodiment, such as Figure 2 As shown, a method for determining the percolation properties of a carbon black network is provided, which can be applied to... Figure 1 Taking terminal 102 as an example, the explanation includes:

[0052] Step S202: Based on the model parameters, construct the percolation model of the carbon black network in three-dimensional space.

[0053] The model parameters can refer to the initial conditions and constraints used to construct the three-dimensional percolation model, including but not limited to the particle size or particle size distribution of carbon black particles, the spatial size or geometry of the three-dimensional space, the connection distance between particles (such as the critical distance of the tunneling effect), the concentration or distribution density of carbon black particles, the number of carbon black particle sets composed of carbon black particles, and the range of the number of carbon black particles contained in each carbon black particle set.

[0054] The three-dimensional space can be a virtual modeling region that simulates the carbon black network, such as a three-dimensional cube or other shape with clear boundaries, which can provide a spatial range for the distribution of carbon black particles.

[0055] The percolation model of the carbon black network can be a mathematical and physical model used to describe the distribution of carbon black particles in three-dimensional space and how they are interconnected. The percolation model can be used to simulate the process of carbon black particles forming a conductive network and to evaluate whether the carbon black network has reached the percolation state.

[0056] The percolation model is used to simulate the distribution of individual carbon black particles in the carbon black network in three-dimensional space.

[0057] In practice, the terminal can distribute carbon black particles in three-dimensional space according to model parameters to form an initial network structure. The positions of the carbon black particles are initialized according to particle distribution rules (random distribution, clustered distribution). Simultaneously, the connection relationships between carbon black particles are set according to particle connection rules (the distance between two carbon black particles cannot be less than a set critical value, which can be the tunneling distance). Through this step, the terminal obtains the initially constructed percolation model, providing a foundation for subsequent particle insertion and model update steps.

[0058] Step S204: New carbon black particles are gradually inserted into the percolation model to obtain the updated percolation model.

[0059] Since the progressive insertion of carbon black particles can alter the carbon black particle distribution, connectivity, and conductive paths in the original percolation model, an updated percolation model can be obtained after the insertion of new carbon black particles. This updated percolation model can be used to reflect the dynamic changes in the carbon black network structure after the insertion of carbon black particles.

[0060] In practice, the terminal can gradually add carbon black particles based on the original percolation model. At each step, one or more carbon black particles can be inserted, and the target conductive path can be searched among the multiple carbon black particles in the updated percolation model. If no target conductive path is found, the next step of carbon black particle insertion can be carried out until the target conductive path is found among the multiple carbon black particles in the updated percolation model.

[0061] In practice, the terminal gradually inserts new carbon black particles into the percolation model. This can be done by randomly generating new carbon black particle positions in a uniform distribution within three-dimensional space; or by prioritizing insertion at locations with efficient connections (such as near existing conductive clusters) based on the distribution of existing particles. After each insertion of a new carbon black particle, it is checked whether it meets the connection conditions (such as whether it satisfies the tunneling distance); otherwise, the position is regenerated.

[0062] Step S206: Search for target conductive paths among the multiple carbon black particles included in the updated percolation model.

[0063] The updated percolation model can be a three-dimensional model that includes the current distribution and connection relationships of all carbon black particles after inserting new carbon black particles into the original percolation model and updating it, reflecting the real-time state of the carbon black network.

[0064] The target conductive path is a conductive path that runs through the first and second surfaces in three-dimensional space; the height difference between the first and second surfaces in three-dimensional space is greater than the difference threshold.

[0065] The target conductive path can refer to the interconnected path formed between carbon black particles in the percolation model through physical contact or tunneling effect, marking the formation of the percolation state.

[0066] The first and second surfaces can be two surfaces in three-dimensional space with a significant height difference, such as the upper and lower surfaces in three-dimensional space, or the top and bottom of a percolation model. Optionally, the difference threshold can be 80% or 90% of the height in three-dimensional space.

[0067] In one embodiment, searching for a target conductive path among multiple carbon black particles included in the updated percolation model can be achieved using breadth-first search (BFS) or depth-first search (DFS) between the first and second surfaces. Specifically, the terminal can sequentially traverse the carbon black particles in three-dimensional space, searching for connecting paths from carbon black particles on the first surface to those on the second surface. When the distance between carbon black particles is less than a preset tunneling distance or physical contact distance, the two carbon black particles are considered connected. The system then recursively or iteratively determines whether the current carbon black particle can connect the first and second surfaces through existing connectivity. During the path search process, the found path information can be recorded to analyze the impact of different carbon black particle distributions on the conductive path. Using search algorithms such as BFS or DFS, connecting paths between upper and lower surfaces can be efficiently found in a large-scale three-dimensional space, improving the accuracy and stability of path searching.

[0068] In practice, the updated percolation model can be searched for the target conductive path multiple times. This records the number of times the target conductive path is successfully found in the updated percolation model, and the percolation probability is calculated. This percolation probability can be used to evaluate percolation performance. Specifically, the percolation probability can be the probability of successfully finding the target conductive path under specific carbon black particle distribution conditions, and can be used to quantify the likelihood of the percolation model reaching the percolation state.

[0069] Step S208: Update the model parameters and return to the step of constructing a percolation model of the carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met.

[0070] The updated model parameters can be key parameters of the percolation model, such as particle size, particle distribution density, particle content, and connection distance. The updated model parameters are used to reflect changes in carbon black particle distribution and electrical conductivity under different conditions, thereby analyzing their impact on percolation performance.

[0071] After updating the model parameters, return to step S202 to reconstruct the percolation model of the carbon black network. This is an iterative loop process that continues until a preset loop termination condition is met. The loop termination condition can be used to determine whether the loop has terminated, and may include determining whether all model parameters such as particle size and particle content have been tested, or whether the preset number of loops has been reached.

[0072] For example, updating model parameters can be done by changing the particle size of carbon black particles, such as adjusting it from 10 nanometers (nm) to 15 nanometers (nm); it can be done by changing the effective connection distance of the tunneling effect between carbon black particles to reflect different conductivity conditions; or it can be done by changing the content of carbon black particles.

[0073] Step S210: Determine the percolation performance of the carbon black network based on the probability of finding the target conductive path in multiple loops.

[0074] In this context, multiple iterations can refer to the process of updating model parameters, rebuilding the percolation model, and conducting simulations multiple times.

[0075] In the specific implementation, in each loop, a percolation model of the carbon black network is first constructed in three-dimensional space based on the model parameters. Then, new carbon black particles are gradually inserted into the percolation model. This gradual insertion can involve increasing the number of carbon black particles one at a time, rather than adding all the carbon black particles at once. After inserting one or more new carbon black particles, a search for the target conductive path is performed. As new carbon black particles are gradually inserted, the probability of finding the target conductive path changes continuously. After each insertion of a carbon black particle, a path search is performed on the entire updated percolation model to determine if a connected path exists from the first surface to the second surface. If a connected path is found, it is recorded as "successful"; otherwise, the next carbon black particle insertion continues until the target conductive path is found among multiple carbon black particles in the updated percolation model. Finally, based on the number of successful searches for the target conductive path and the total number of searches in the current updated percolation model, the probability of finding the target conductive path, i.e., the percolation probability, is obtained. For example, if only a small number of new carbon black particles are needed to find the target conductive path, it indicates that the percolation model built based on these parameters has a high percolation probability; conversely, if a large number of new carbon black particles are required to find the target conductive path, it indicates that the percolation model built based on these parameters has a low percolation probability. After finding the target conductive path, the model parameters are updated, and the next iteration is performed until the loop termination condition is met. Then, based on the probability of finding the target conductive path in each iteration, the percolation performance of the carbon black network is determined.

[0076] The probability of finding the target conductive path can also be called the percolation probability, which reflects the conductivity of the percolation model under the given model parameters. The level of the percolation probability, to a certain extent, reflects the degree of development of the conductive network of carbon black particles in the percolation system.

[0077] The percolation performance can include the conductivity and global connectivity of the carbon black network. The percolation probability can be used to quantify the conductivity and percolation behavior of the carbon black network under different conditions.

[0078] In practice, the percolation probabilities of multiple cycles can be summarized, and the relationship curves between different model parameters (such as particle size or particle content) and percolation probabilities can be plotted to obtain percolation probability curves under different model parameters. This allows for the simulation of the bonding mode of carbon black particles under different particle sizes and contents, and the determination of the influence of different particle sizes and contents on percolation performance. This helps to understand how the distribution and connection mode of carbon black particles in the matrix affects the overall conductivity of the material.

[0079] In the above-mentioned method for determining the percolation performance of the carbon black network, a percolation model of the carbon black network is constructed in three-dimensional space based on model parameters. This percolation model simulates the distribution of individual carbon black particles in the three-dimensional space. New carbon black particles are progressively inserted into the percolation model to obtain an updated percolation model. A target conductive path is searched among the multiple carbon black particles included in the updated percolation model. This target conductive path is a conductive path that traverses the first and second surfaces in three-dimensional space, and the height difference between the first and second surfaces in three-dimensional space is greater than a threshold value. The model parameters are updated, and the process returns to the step of constructing the percolation model of the carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met. The percolation performance of the carbon black network is determined based on the probability of finding the target conductive path in each of the multiple loops. By progressively inserting carbon black particles and dynamically updating the percolation model, combined with the search for the target conductive path and the statistics of percolation probability, the distribution and connection characteristics of carbon black particles can be accurately simulated in three-dimensional space, constructing a high-precision percolation model. This significantly improves the accuracy of percolation performance determination, providing a scientific basis for optimizing the formulation of semi-conductive shielding materials for high-voltage cables, and further enhancing the conductivity, processing performance, and overall cable performance of the material.

[0080] In another embodiment, based on model parameters, a percolation model of a carbon black network is constructed in three-dimensional space, including: obtaining a preset carbon black particle diameter, a preset number of carbon black particle sets, and a preset number of carbon black particles contained in each carbon black particle set; during the construction of the current carbon black particle set, generating several new carbon black particles around the existing carbon black particles in the current carbon black particle set according to a preset particle distance; the diameter of the several new carbon black particles conforms to the preset carbon black particle diameter; and, provided that the several new carbon black particles are located in three-dimensional space and do not overlap with other carbon black particles in the current carbon black particle set, adding the several new carbon black particles to the current carbon black particle set. Then return to the step of generating a number of new carbon black particles around the existing carbon black particles in the current carbon black particle set according to the preset particle distance, until the number of carbon black particles in the current carbon black particle set meets the preset number of carbon black particles; continue to construct the next carbon black particle set, take the next carbon black particle set as the current carbon black particle set, and return to the step of generating a number of new carbon black particles around the existing carbon black particles in the current carbon black particle set according to the preset particle distance during the construction of the current carbon black particle set, until multiple carbon black particle sets that meet the preset number of carbon black particle sets are generated; based on the multiple carbon black particle sets, construct the percolation model of the carbon black network in three-dimensional space.

[0081] In practical applications, carbon black exhibits a multi-layered, structured distribution in the matrix resin. Individual carbon black particles, acting as basic units, are uniformly distributed in the resin through the action of surfactants or dispersants, forming a primary particle distribution. Subsequently, these particles attract each other through van der Waals forces, forming grape-like aggregates composed of several to dozens of primary particles. These grape-like aggregates are distributed randomly and with a certain orientation in the matrix, constituting a grape-like aggregate distribution. As the carbon black content increases, the distance between the grape-like aggregates decreases, making it easier to form conductive pathways. These pathways are achieved through direct contact or tunneling effects between carbon black particles, thus constructing an effective conductive network in the matrix resin. Furthermore, the interfacial forces between carbon black particles and the resin also affect their distribution in the matrix. Good interfacial interactions contribute to more uniform particle dispersion and enhance the formation of the conductive network, collectively determining the conductivity of carbon black-filled composite materials. Therefore, this distribution pattern can be mimicked to construct carbon black particle assemblies, and subsequently, a percolation model of the carbon black network can be built.

[0082] Among them, the carbon black particle set can be a grape-like set of carbon black particles. Each set of carbon black particles can be regarded as a local "grape bunch" structure. By combining these sets, an overall carbon black network is formed.

[0083] Optionally, model parameters may include the spatial dimensions in three-dimensional space, the diameter of carbon black particles, the number of carbon black particles, the number of bunches (the number of carbon black particle sets), and the range of the number of spheres in each bunch (the number of carbon black particle sets). Based on these model parameters, multiple bunch-like carbon black particle sets can be generated. Specifically, starting from a random position, a bunch-like carbon black particle set can be generated through an iterative algorithm, ensuring that the newly generated carbon black particles do not overlap with existing carbon black particles and are within a predetermined range. The generated carbon black particles are divided into sets of carbon black particles for a first surface and a second surface, and the corresponding coordinate information is recorded. The recursively generated bunch-like carbon black particles are evenly distributed, avoiding particle overlap and ensuring the rationality and effectiveness of the structure.

[0084] In practice, a starting point can be set in three-dimensional space, and the first carbon black particle is constructed based on the starting point position. The particle size of this carbon black particle conforms to the preset carbon black particle diameter. New carbon black particles are generated from the current carbon black particle at random angles and fixed distances. Each time, several new carbon black particles are generated (for example, 2 to 6). It is checked whether the newly generated carbon black particles are within the range of three-dimensional space and whether they overlap with existing carbon black particles. If both conditions are met, the new carbon black particles can be added to the carbon black particle set. Based on the position of the new carbon black particles, it is determined whether they are located on the first or second surface of three-dimensional space and added to the corresponding list. If the number of carbon black particles in the current carbon black particle set reaches the preset number of carbon black particles, or the number of attempts to generate particles reaches 1000, the generation of the current carbon black particle set can be stopped, and the generation of the next carbon black particle set can continue until the number of carbon black particle sets meets the preset number of carbon black particle sets. Based on multiple carbon black particle sets, a percolation model of the carbon black network is constructed to simulate the distribution and conductivity of carbon black particles in the material.

[0085] For example, the size of the three-dimensional space can be set to 1000nm×1000nm×1000nm, the diameter of the carbon black particles can be adjusted between 10nm and 60nm, the number of particles contained in a single bunch of carbon black particles can be set to 15 to 30, and the number of carbon black particles in a set can be 200 to 300.

[0086] For example, the volume percentage of the generated carbon black particle ensemble in the entire three-dimensional space can be recorded to determine the density of the generated structure. This calculation helps to evaluate the filling effect of carbon black particles in the matrix material.

[0087] The technical solution of this embodiment generates carbon black networks with different properties (such as particle size and density) by adjusting parameters; through step-by-step generation and rigorous inspection, a high-precision carbon black percolation model is constructed in three-dimensional space; it is suitable for simulating the distribution of carbon black particles in actual materials and can be used to study percolation performance or optimize material design.

[0088] In another embodiment, the process of progressively inserting new carbon black particles into the percolation model to obtain an updated percolation model includes: progressively inserting new carbon black particles into the percolation model; determining the conductive group to which the new carbon black particles belong in the percolation model based on the distance between the new carbon black particles and the original carbon black particles in the percolation model, so as to obtain an updated conductive group; the conductive group is a collection of multiple carbon black particles that form a conductive path; and obtaining an updated percolation model based on the updated conductive group.

[0089] Among them, a conductive cluster can refer to a collection of multiple carbon black particles connected by physical contact or tunneling effect. Conductive clusters are the basis for forming conductive paths in the percolation model.

[0090] In practice, new carbon black particles are dynamically inserted into the existing percolation model, gradually expanding or adjusting the conductive network (conductive clusters) within the model. The distance between the new particle and existing particles determines whether it is connected to a specific conductive cluster. If the distance between a new particle and a particle in a conductive cluster is less than a preset connection threshold, the new particle is added to that conductive cluster. If a new particle simultaneously satisfies the connection conditions with multiple conductive clusters, these clusters are merged into a larger cluster. If a new particle is not connected to any existing particle, a new independent conductive cluster is formed. The new carbon black particles are then regrouped with existing particles to form updated conductive clusters. Based on these updated conductive clusters, the structure of the entire percolation model is adjusted to obtain an updated percolation model, which reflects the current distribution and connectivity of the carbon black particles.

[0091] The technical solution of this embodiment reflects the process of carbon black particles gradually connecting to form a conductive network from independent distribution. By updating the conductive clusters in real time, the model accurately describes the connectivity and conductivity of carbon black particles. This provides a reliable modeling method for studying the relationship between carbon black particle concentration, distribution, and percolation performance. By progressively inserting carbon black particles and dynamically updating the conductive clusters and percolation model, accurate simulation of the carbon black network evolution process is achieved. This method is suitable for studying the formation law of conductive networks and provides an important basis for optimizing material formulations and improving conductivity.

[0092] In another embodiment, determining the conductive group to which the new carbon black particles belong in the percolation model based on the distance between the new carbon black particles and the original carbon black particles in the percolation model includes: identifying target particles from the original carbon black particles whose distances are less than a preset limit distance based on the distance between the new carbon black particles and the original carbon black particles in the percolation model; if each target particle belongs to the same conductive group, then the new carbon black particles are determined to belong to the same conductive group; if each target particle belongs to at least one different conductive group, then the different conductive groups are merged into a new conductive group, and the new carbon black particles are determined to belong to the new conductive group.

[0093] The preset limit distance is the critical distance used to determine whether two particles can connect, and it is usually set based on the range of physical contact or tunneling effect.

[0094] The target particle can be a carbon black particle that meets the preset limit distance condition with the new carbon black particle among the existing carbon black particles.

[0095] In practice, each time a new carbon black particle is inserted, the composition of the conductive group is adjusted according to the affiliation of the new carbon black particle, such as expanding an existing conductive group, merging multiple conductive groups, or creating a new conductive group (if the new particle is not connected to any target particle).

[0096] For example, in the percolation model, when interpolating new carbon black particles, it is necessary to determine whether the carbon black particle forms a new independent conductive group and connects to an existing conductive group, or whether it connects two independent conductive groups. Therefore, it is necessary to use the neighborhood relationship in the data structure to determine whether there are other carbon black particles around the interpolated carbon black particle within a given range (within a preset limit distance). For each interpolated carbon black particle, its neighborhood is checked to find nearby carbon black particles. The label values ​​of the neighboring carbon black particles are recorded to identify the conductive group to which they belong. The neighboring carbon black particles found during the search are connected. Each time a new carbon black particle is interpolated, it is immediately labeled, and its status information is recorded. As carbon black particles are interpolated step by step, after each interpolation, the neighboring particles of the new carbon black particle are searched, and their label values ​​are checked. If carbon black particles with the same label value are found within a given preset limit distance, the new carbon black particle is added to the same conductive group. If carbon black particles with different label values ​​are found, the two conductive groups are connected together and the label values ​​are unified. Alternatively, a conductive group can be randomly selected, and the label values ​​of all related carbon black particles can be updated to make them consistent. This ensures that the relationship between particles and conductive groups can be correctly judged and processed during the particle interpolation process, and realizes the dynamic generation and connection of conductive groups.

[0097] As an example, in a pre-constructed percolation model, setting a preset limit distance for the connection between carbon black particles is crucial. If the spacing between carbon black particles is small, leakage current will be generated in the medium, which will also increase the conductivity of the system. From the formula for the tunneling probability of charge carriers crossing the barrier, it can be calculated that the tunneling effect decreases exponentially with increasing distance; therefore, the preset limit distance can be set to 2 nanometers (nm).

[0098] As another example, a preset limiting distance can be determined based on the particle size of the carbon black particles. Assuming the particle size of the carbon black particles is w, the limiting distance d between the particles can be determined as: In the percolation model, model parameters such as model size, particle size, and particle connection conditions are set. Particles are interpolated step by step in the percolation model, and repeated searches and connections are made to find other carbon black particles within a preset limit distance range in the 360-degree direction of any particle.

[0099] The technical solution of this embodiment determines the relationship between the newly inserted carbon black particles and existing carbon black particles based on their positions, identifies the conductive group to which they belong, and merges the conductive groups when necessary. This enables dynamic adjustment of the conductive network, reflects the gradual connection and evolution process of the carbon black network, and can reflect the impact of new particle insertion on the connectivity of the conductive network in real time, supporting the gradual evolution of the carbon black network. By merging conductive groups, it ensures that the conductive path of the model gradually forms and tends to be complete. By filtering target particles by distance, only particles that may be connected are calculated, reducing unnecessary operations.

[0100] In another embodiment, searching for a target conductive path among multiple carbon black particles included in the updated percolation model includes: searching for the largest conductive group among the conductive groups included in the updated percolation model; the largest conductive group is the conductive group containing the most carbon black particles; and determining the target conductive path from the conductive paths contained in the largest conductive group if the largest conductive group traverses a first surface and a second surface in three-dimensional space.

[0101] The largest conductive cluster is the one containing the most carbon black particles, representing the most important conductive network in the model. In practice, all conductive clusters in the updated percolation model can be traversed, the number of carbon black particles in each cluster can be counted, and the conductive cluster with the most particles is identified as the largest conductive cluster.

[0102] The largest conductive cluster must connect the first and second surfaces in three-dimensional space; that is, the largest conductive cluster must contain a connected path from the first surface to the second surface. If the largest conductive cluster traverses the three-dimensional space, the traversing path is selected from all its conductive paths as the target conductive path. The target conductive path is the most important connected path in the model, indicating that the model has reached a percolation state.

[0103] For example, as the number of interpolated carbon black particles in the percolation model increases, the connections between the carbon black particles form conductive clusters. When the largest conductive cluster penetrates the first and second surfaces of the system (e.g., the upper and lower surfaces), the percolation model can be considered to have reached the percolation state. If the spatial dimensions of the three-dimensional space are a square or cube with a side length of 1000, and the number of carbon black particles contained is n with a volume fraction of V, then the relationship between V and n when the percolation state is reached can be calculated by the following formula:

[0104] ;

[0105] Where r is the particle size and l is the preset limit distance between carbon black particles.

[0106] The technical solution in this embodiment finds the target conductive path that can penetrate the upper and lower surfaces of the carbon black network by searching and analyzing the largest conductive cluster in the percolation model, thus achieving a precise evaluation of the global conductivity of the carbon black network. By determining whether the target conductive path penetrates the three-dimensional space, the percolation state can be dynamically analyzed, providing a scientific basis for studying the percolation performance of the carbon black network.

[0107] In another embodiment, the percolation performance of the carbon black network is determined based on the probability of finding the target conductive path in multiple iterations, including: determining that the updated percolation model has reached a percolation state when the probability of finding the target conductive path is greater than or equal to a probability threshold; the percolation state is the state in which the target conductive path exists in the updated percolation model; and determining the percolation threshold of the carbon black network based on the average carbon black particle content corresponding to when the updated percolation model reaches the percolation state in multiple iterations.

[0108] In the specific implementation, in each loop, the probability of finding the target conductive path is calculated based on the updated percolation model. If the probability of finding the target conductive path is greater than or equal to a preset probability threshold (e.g., 50%), the updated percolation model can be considered to have reached the percolation state. The percolation state means that a conductive path from the first surface to the second surface in three-dimensional space already exists in the carbon black network.

[0109] In each iteration, the carbon black particle content at which the percolation model reaches the percolation state is recorded. The carbon black particle content can refer to the proportion or number of carbon black particles in the total space of the model. The carbon black particle content corresponding to the percolation state across multiple iterations is summarized, and the average value is used as the percolation threshold for the carbon black network.

[0110] The percolation threshold can be used to characterize how easily a carbon black network reaches a percolation state. A higher percolation threshold indicates that a higher particle concentration is required for the carbon black network to form conductive pathways; a lower percolation threshold indicates that a conductive state can be achieved at a lower concentration.

[0111] For example, the percolation threshold obtained through a single modeling step is random. To eliminate random errors, multiple iterations are performed, interpolating carbon black particles multiple times in each iteration until the percolation model reaches a percolation state. The carbon black particle content is calculated, and the average carbon black particle content in each iteration is calculated. This average value can be determined as the percolation threshold, and percolation probability curves are plotted for different particle sizes. The percolation threshold represents the ease with which the carbon black network reaches a percolation state. If the percolation probability of the carbon black network is not less than 50%, the carbon black network can be considered to have reached a percolation state. The level of the percolation probability, to some extent, reflects the degree of development of the conductive network of particles in the percolation system.

[0112] The technical solution of this embodiment dynamically evaluates the conductivity of a carbon black network and accurately determines the percolation state by setting a probability threshold. By using the percolation threshold, the influence of carbon black particle distribution on the network's conductivity is quantified, improving the accuracy of determining percolation performance and providing a scientific basis for optimizing the design and production of conductive materials. This method can simulate the binding mode of carbon black particles under different parameters such as different particle sizes and contents, and analyze the impact of changes in particle content and size on the overall percolation threshold.

[0113] In another embodiment, a three-dimensional structure and a visual image of the conductive path of the percolation model can be generated. The results are plotted and saved to a designated folder using a graphics library, generating easily viewable results and original-size result images. The probability of finding the target conductive path in multiple simulations is recorded, and the overall algorithm runtime and the runtime of each step are calculated and printed. Relevant images are displayed when needed. The generated three-dimensional structure and path are graphically displayed, facilitating observation and analysis, and providing strong support for further research.

[0114] For the convenience of those skilled in the art, Figure 3 An exemplary schematic diagram of a conductive path is provided.

[0115] For the convenience of those skilled in the art, Figure 4 An exemplary diagram illustrating the changes in the percolation threshold and percolation probability of a percolation model is provided.

[0116] It should be understood that although the steps in the flowcharts of the embodiments described above are shown sequentially according to the arrows, these steps are not necessarily executed in the order indicated by the arrows. Unless explicitly stated herein, there is no strict order restriction on the execution of these steps, and they can be executed in other orders. Moreover, at least some steps in the flowcharts of the embodiments described above may include multiple steps or multiple stages. These steps or stages are not necessarily completed at the same time, but can be executed at different times. The execution order of these steps or stages is not necessarily sequential, but can be performed alternately or in turn with other steps or at least some of the steps or stages of other steps.

[0117] Based on the same inventive concept, this application also provides a device for determining the percolation performance of a carbon black network to implement the above-described method for determining the percolation performance of a carbon black network. The solution provided by this device is similar to the solution described in the above-described method. Therefore, the specific limitations of one or more embodiments of the device for determining the percolation performance of a carbon black network provided below can be found in the limitations of the method for determining the percolation performance of a carbon black network described above, and will not be repeated here.

[0118] In one exemplary embodiment, such as Figure 5 As shown, an apparatus for determining the percolation properties of a carbon black network is provided, comprising:

[0119] The construction module 510 is used to construct a percolation model of a carbon black network in three-dimensional space based on model parameters; the percolation model is used to simulate the distribution of each carbon black particle in the carbon black network in the three-dimensional space.

[0120] The update module 520 is used to gradually insert new carbon black particles into the percolation model to obtain an updated percolation model.

[0121] Search module 530 is used to search for target conductive paths among multiple carbon black particles included in the updated percolation model; the target conductive path is a conductive path that runs through a first surface and a second surface in the three-dimensional space; the height difference between the first surface and the second surface in the three-dimensional space is greater than a difference threshold.

[0122] The update module 520 is also used to update the model parameters and return to the step of constructing a percolation model of a carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met.

[0123] The determination module 540 is used to determine the percolation performance of the carbon black network based on the probability of finding the target conductive path in multiple loops.

[0124] In one embodiment, the updating module 520 is specifically used to progressively insert new carbon black particles into the percolation model; determine the conductive group to which the new carbon black particles belong in the percolation model based on the distance between the new carbon black particles and the original carbon black particles in the percolation model, so as to obtain an updated conductive group; the conductive group is a collection of multiple carbon black particles that form a conductive path; and obtain the updated percolation model based on the updated conductive group.

[0125] In one embodiment, the updating module 520 is specifically used to determine target particles whose distance is less than a preset limit distance from the original carbon black particles based on the distance between the new carbon black particles and the original carbon black particles in the percolation model; if each of the target particles belongs to the same conductive group, then the new carbon black particles are determined to belong to the same conductive group; if each of the target particles belongs to at least one different conductive group, then the different conductive groups are merged into a new conductive group, and the new carbon black particles are determined to belong to the new conductive group.

[0126] In one embodiment, the search module 530 is specifically used to search for the largest conductive group among the conductive groups included in the updated percolation model; the largest conductive group is the conductive group containing the largest number of carbon black particles; and when the largest conductive group penetrates the first surface and the second surface in the three-dimensional space, the target conductive path is determined from the conductive paths contained in the largest conductive group.

[0127] In one embodiment, the determining module 540 is specifically configured to determine that the updated percolation model has reached a percolation state when the probability of finding the target conductive path is greater than or equal to a probability threshold; the percolation state is the state in which the target conductive path exists in the updated percolation model; and to determine the percolation threshold of the carbon black network based on the average carbon black particle content corresponding to when the updated percolation model reaches the percolation state in the multiple iterations; the percolation threshold is used to characterize the ease with which the carbon black network reaches the percolation state.

[0128] In one embodiment, the construction module 510 is specifically used to obtain the preset carbon black particle diameter, the preset number of carbon black particle sets, and the preset number of carbon black particles contained in each carbon black particle set from the model parameters; during the construction of the current carbon black particle set, according to the preset particle distance, several new carbon black particles are generated around the original carbon black particles in the current carbon black particle set; the diameter of the several new carbon black particles conforms to the preset carbon black particle diameter; when the several new carbon black particles are located in the three-dimensional space and do not overlap with other carbon black particles in the current carbon black particle set, the several new carbon black particles are added to the current carbon black particle set, and the process returns to the preset particle distance. The process involves generating several new carbon black particles around the existing carbon black particles in the current carbon black particle set according to a preset particle distance, until the number of carbon black particles in the current carbon black particle set meets the preset number of carbon black particles. This process continues until multiple carbon black particle sets that meet the preset number of carbon black particles are generated. Based on these multiple carbon black particle sets, a percolation model of the carbon black network is constructed in the three-dimensional space.

[0129] Each module in the aforementioned device for determining the percolation performance of carbon black networks can be implemented entirely or partially through software, hardware, or a combination thereof. These modules can be embedded in hardware within or independently of the processor in a computer device, or stored in software within the memory of a computer device, so that the processor can invoke and execute the corresponding operations of each module.

[0130] In one exemplary embodiment, a computer device is provided, which may be a terminal, and its internal structure diagram may be as follows: Figure 6 As shown, the computer device includes a processor, memory, input / output interface, communication interface, display unit, and input device. The processor, memory, and input / output interface are connected via a system bus, and the communication interface, display unit, and input device are also connected to the system bus via the input / output interface. The processor provides computing and control capabilities. The memory includes a non-volatile storage medium and internal memory. The non-volatile storage medium stores the operating system and computer programs. The internal memory provides an environment for the operation of the operating system and computer programs in the non-volatile storage medium. The input / output interface is used for exchanging information between the processor and external devices. The communication interface is used for wired or wireless communication with external terminals; wireless communication can be achieved through Wi-Fi, mobile cellular networks, Near Field Communication (NFC), or other technologies. When executed by the processor, the computer program implements a method for determining the percolation performance of a carbon black network. The display unit is used to form a visually visible image and can be a display screen, a projection device, or a virtual reality imaging device. The display screen can be an LCD screen or an e-ink screen. The input device of the computer device can be a touch layer covering the display screen, or buttons, trackballs, or touchpads set on the casing of the computer device, or external keyboards, touchpads, or mice, etc.

[0131] Those skilled in the art will understand that Figure 6 The structure shown is merely a block diagram of a portion of the structure related to the present application and does not constitute a limitation on the computer device to which the present application is applied. Specific computer devices may include more or fewer components than those shown in the figure, or combine certain components, or have different component arrangements.

[0132] In one exemplary embodiment, a computer device is provided, including a memory and a processor, wherein the memory stores a computer program, and the processor executes the computer program to implement the steps in the above-described method embodiments.

[0133] In one embodiment, a computer-readable storage medium is provided having a computer program stored thereon, which, when executed by a processor, implements the steps in the above method embodiments.

[0134] In one embodiment, a computer program product is provided, including a computer program that, when executed by a processor, implements the steps in the above method embodiments.

[0135] It should be noted that the user information (including but not limited to user device information, user personal information, etc.) and data (including but not limited to data used for analysis, data stored, data displayed, etc.) involved in this application are all information and data authorized by the user or fully authorized by all parties, and the collection, use and processing of the relevant data must comply with relevant regulations.

[0136] Those skilled in the art will understand that all or part of the processes in the methods of the above embodiments can be implemented by a computer program instructing related hardware. The computer program can be stored in a non-volatile computer-readable storage medium, and when executed, it can include the processes of the embodiments of the above methods. Any references to memory, databases, or other media used in the embodiments provided in this application can include at least one of non-volatile memory and volatile memory. Non-volatile memory can include read-only memory (ROM), magnetic tape, floppy disk, flash memory, optical memory, high-density embedded non-volatile memory, resistive random access memory (ReRAM), magnetic random access memory (MRAM), ferroelectric random access memory (FRAM), phase change memory (PCM), graphene memory, etc. Volatile memory can include random access memory (RAM) or external cache memory, etc. By way of illustration and not limitation, RAM can take many forms, such as Static Random Access Memory (SRAM) or Dynamic Random Access Memory (DRAM). The databases involved in the embodiments provided in this application may include at least one type of relational database and non-relational database. Non-relational databases may include, but are not limited to, blockchain-based distributed databases. The processors involved in the embodiments provided in this application may be general-purpose processors, central processing units, graphics processing units, digital signal processors, programmable logic devices, quantum computing-based data processing logic devices, artificial intelligence (AI) processors, etc., and are not limited to these.

[0137] The technical features of the above embodiments can be combined in any way. For the sake of brevity, not all possible combinations of the technical features in the above embodiments are described. However, as long as there is no contradiction in the combination of these technical features, they should be considered to be within the scope of this application.

[0138] The embodiments described above are merely illustrative of several implementation methods of this application, and while the descriptions are specific and detailed, they should not be construed as limiting the scope of this patent application. It should be noted that those skilled in the art can make various modifications and improvements without departing from the concept of this application, and these all fall within the protection scope of this application. Therefore, the protection scope of this application should be determined by the appended claims.

Claims

1. A method for determining the percolation properties of a carbon black network, characterized in that, The method includes: Based on model parameters, a percolation model of a carbon black network is constructed in three-dimensional space; the percolation model is used to simulate the distribution of each carbon black particle in the carbon black network in the three-dimensional space. New carbon black particles are gradually inserted into the percolation model; Based on the distance between the new carbon black particles and the original carbon black particles in the percolation model, the conductive group to which the new carbon black particles belong in the percolation model is determined to obtain the updated conductive group; the conductive group is a collection of multiple carbon black particles that form a conductive path. Based on the updated conductive group, the updated percolation model is obtained; The target conductive path is searched among the multiple carbon black particles included in the updated percolation model; the target conductive path is a conductive path that runs through the first surface and the second surface in the three-dimensional space; the height difference between the first surface and the second surface in the three-dimensional space is greater than the difference threshold. Update the model parameters and return to the step of constructing a percolation model of a carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met; If the probability of finding the target conductive path is greater than or equal to a probability threshold, the updated percolation model is determined to have reached a percolation state; the percolation state is the state in which the target conductive path exists in the updated percolation model. The percolation threshold of the carbon black network is determined based on the average carbon black particle content corresponding to the percolation state when the updated percolation model reaches the percolation state in multiple iterations; the percolation threshold is used to characterize the ease with which the carbon black network reaches the percolation state.

2. The method according to claim 1, characterized in that, The step of determining the conductive group to which the new carbon black particles belong in the percolation model based on the distance between the new carbon black particles and the original carbon black particles in the percolation model includes: Based on the distance between the new carbon black particles and the original carbon black particles in the percolation model, target particles whose distance is less than a preset limit distance are determined from the original carbon black particles. If each of the target particles belongs to the same conductive group, then the new carbon black particles are determined to belong to the same conductive group. If each of the target particles belongs to at least one different conductive group, then the different conductive groups are merged into a new conductive group, and the new carbon black particles are determined to belong to the new conductive group.

3. The method according to claim 1, characterized in that, The process of searching for the target conductive path among the multiple carbon black particles included in the updated percolation model includes: The maximum conductive group is searched among the conductive groups included in the updated percolation model; the maximum conductive group is the conductive group containing the largest number of carbon black particles. In the case where the largest conductive group penetrates the first and second surfaces in the three-dimensional space, the target conductive path is determined from the conductive paths contained in the largest conductive group.

4. The method according to claim 1, characterized in that, The percolation model for constructing a carbon black network in three-dimensional space based on model parameters includes: Obtain the preset carbon black particle diameter, preset carbon black particle set quantity, and preset carbon black particle quantity contained in each carbon black particle set from the model parameters. During the construction of the current carbon black particle set, according to the preset particle distance, several new carbon black particles are generated around the original carbon black particles in the current carbon black particle set; the diameter of the several new carbon black particles conforms to the preset carbon black particle diameter. When the several new carbon black particles are located in the three-dimensional space and do not overlap with other carbon black particles in the current carbon black particle set, the several new carbon black particles are added to the current carbon black particle set, and the process returns to the step of generating several new carbon black particles around the original carbon black particles in the current carbon black particle set according to the preset particle distance, until the number of carbon black particles contained in the current carbon black particle set meets the preset number of carbon black particles; Continue to construct the next set of carbon black particles, take the next set of carbon black particles as the current set of carbon black particles, and return to the step of generating a number of new carbon black particles around the original carbon black particles in the current set of carbon black particles according to the preset particle distance during the construction of the current set of carbon black particles, until multiple sets of carbon black particles that meet the preset number of carbon black particles are generated. Based on the multiple sets of carbon black particles, a percolation model of the carbon black network is constructed in the three-dimensional space.

5. A device for determining the percolation properties of a carbon black network, characterized in that, The device includes: A construction module is used to construct a percolation model of a carbon black network in three-dimensional space based on model parameters; the percolation model is used to simulate the distribution of each carbon black particle in the carbon black network in the three-dimensional space. An update module is used to progressively insert new carbon black particles into the percolation model; based on the distance between the new carbon black particles and the original carbon black particles in the percolation model, the conductive group to which the new carbon black particles belong in the percolation model is determined to obtain an updated conductive group; the conductive group is a collection of multiple carbon black particles that form a conductive path; based on the updated conductive group, an updated percolation model is obtained. The search module is used to search for target conductive paths among multiple carbon black particles included in the updated percolation model; the target conductive path is a conductive path that runs through a first surface and a second surface in the three-dimensional space; the height difference between the first surface and the second surface in the three-dimensional space is greater than a difference threshold. The update module is also used to update the model parameters and return to the step of constructing a percolation model of a carbon black network in three-dimensional space based on the model parameters, until the loop termination condition is met. A determination module is used to determine that the updated percolation model has reached a percolation state when the probability of finding the target conductive path is greater than or equal to a probability threshold; the percolation state is the state in which the target conductive path exists in the updated percolation model; based on the average carbon black particle content corresponding to the updated percolation model reaching the percolation state in multiple iterations, a percolation threshold for the carbon black network is determined; the percolation threshold is used to characterize the ease with which the carbon black network reaches the percolation state.

6. A computer device comprising a memory and a processor, wherein the memory stores a computer program, characterized in that, When the processor executes the computer program, it implements the steps of the method according to any one of claims 1 to 4.

7. A computer-readable storage medium having a computer program stored thereon, characterized in that, When the computer program is executed by a processor, it implements the steps of the method according to any one of claims 1 to 4.

8. A computer program product, comprising a computer program, characterized in that, When the computer program is executed by a processor, it implements the steps of the method according to any one of claims 1 to 4.

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