一种钙钛矿致密覆盖绒面硅的叠层太阳能电池及其制备方法

By spraying a fine particle layer into perovskite/silicon tandem solar cells, the problem of perovskite film not being able to completely cover the silicon textured surface is solved, achieving dense coverage, improving photoelectric conversion efficiency, and making it suitable for large-area rapid fabrication of high-efficiency perovskite/silicon tandem cells.

CN120112047BActive Publication Date: 2026-07-17XI AN JIAOTONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XI AN JIAOTONG UNIV
Filing Date
2025-03-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, perovskite/silicon tandem solar cells suffer from leakage current and low efficiency due to size mismatch, which prevents the perovskite film from completely covering the silicon textured surface. Furthermore, existing methods cannot achieve dense coverage without changing the textured surface size, thus affecting photoelectric conversion efficiency.

Method used

A layer of fine particles with a size of 100-1000 nm is sprayed between the pyramid tip and the perovskite layer of a textured silicon substrate solar cell. By controlling the coverage and thickness of the particle layer, a dense coverage of the perovskite layer is achieved, and a tandem solar cell is fabricated using a one-step solution method.

Benefits of technology

It effectively solves the problems of uncovered tips and poor filling between perovskite films and textured silicon wafer substrates, improves the coverage quality and filling effect of perovskite films, enhances photoelectric conversion efficiency, and is suitable for large-area rapid fabrication of high-efficiency perovskite/silicon tandem solar cells.

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Abstract

本发明公开了一种钙钛矿致密覆盖绒面硅的叠层太阳能电池及其制备方法,属于太阳能电池薄膜制备技术领域。技术方案为:在绒面硅底电池的金字塔塔尖和钙钛矿层之间喷涂有微细颗粒层,且在距离塔尖0~2000 nm之间任意高度至塔尖之间覆盖有所述微细颗粒层,微细颗粒层能够使钙钛矿层致密覆盖金字塔塔尖。在微细颗粒的作用下,钙钛矿溶液对绒面硅片基体的金字塔起伏界面具有强制润湿和控制形核作用,有效将顶部难以粘附在塔尖的钙钛矿溶液通过亲水作用,在表面张力的驱动下浸润并粘附在绒面上,微细颗粒的相互界面可以提供更多的形核位点。同时本发明通过喷涂方法的批量化工艺为快速制造高效大面积钙钛矿 / 硅叠层电池提供了良好的基础条件。
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