ZSM-5分子筛、其制备方法及应用

By employing two-stage crystallization processes and a pH adjuster, combined with ball milling and calcination, the problems of large size and small specific surface area of ​​ZSM-5 molecular sieves were solved, resulting in the preparation of nanoscale ZSM-5 molecular sieves and improved catalytic performance.

CN120229740BActive Publication Date: 2026-07-17PETROCHINA CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
PETROCHINA CO LTD
Filing Date
2023-12-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The existing ZSM-5 molecular sieve has a large crystal size and small specific surface area, and does not have mesoporous characteristics, which limits its application potential in catalytic reactions.

Method used

A two-stage crystallization process was adopted, combined with the use of pH adjuster and ball milling, to regulate the nucleation rate and crystal growth rate. Through multiple crystallization and calcination processes, nanoscale ZSM-5 molecular sieves were finally obtained.

Benefits of technology

The size of ZSM-5 molecular sieve was successfully reduced, its specific surface area was increased, and its catalytic performance was enhanced, making it suitable for catalytic conversion of methanol to olefins, catalytic isomerization of aromatics and aromatic compounds, and catalytic aromatization reactions.

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Abstract

本发明提供了一种ZSM‑5分子筛及其制备方法。该制备方法包括:S1,将硅源、pH调节剂与第一溶剂混合,得到第一混合液;S2,将铝源、模板剂与第一混合液混合,得到第二混合液;S3,对第二混合液依次进行第一晶化处理和第二晶化处理,得到包括第一晶化产物和母液的产物体系;S4,对第一晶化产物和第二溶剂的混合物进行球磨处理,得到包括球磨产物的球磨体系;S5,在第三溶剂中对球磨产物依次进行第三晶化处理和第四晶化处理,得到第二晶化产物;S6,对第二晶化产物进行煅烧处理,得到ZSM‑5分子筛。
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