Hydrolysis catalysts with high acid tolerance

By using catalysts containing mixed metal oxides, alumina, silica and calcium, the problem of existing catalysts being susceptible to toxicity by sulfur and free fatty acids is solved, and an efficient and stable hydrogenolysis reaction is achieved.

CN120268410APending Publication Date: 2025-07-08BASF CORPORATON
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Patent Information

Application Number
CN202510467942.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2015-03-26
Filing Date
2016-03-25
Publication Date
2025-07-08

AI Technical Summary

Technical Problem

The existing catalysts of hydrolyzed fatty acid esters are susceptible to toxicity by sulfur and free fatty acids, resulting in the deactivation of the catalyst and affecting the efficiency and life of the hydrogenolysis.

Method used

A catalyst containing mixed metal oxides, alumina, silica and calcium is used to form highly dispersed copper active sites by calcining the molding material to improve the acid tolerance and stability of the catalyst.

Benefits of technology

It significantly improves the catalyst's tolerance to sulfur and free fatty acids, extends the service life of the catalyst, and maintains high hydrolysis activity.

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Abstract

A catalyst includes a mixed metal oxide, alumina, silica, and calcium, wherein the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced resistance to sulfur-containing compounds and free fatty acids.
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