一种高负载量的分子筛 / 纸浆纤维复合材料及其制备方法和应用

By selectively oxidizing pulp fibers and hydrothermally synthesizing type A molecular sieves, the problems of low molecular sieve loading and poor uniformity on pulp fibers were solved, and a high-loading molecular sieve/pulp fiber composite material was prepared. This composite material was then applied to water-sensitive test paper, achieving a highly sensitive color response.

CN120291395BActive Publication Date: 2026-07-17SOUTH CHINA UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SOUTH CHINA UNIV OF TECH
Filing Date
2025-04-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, molecular sieves have low loading capacity and poor uniformity on pulp fibers, and the bonding stability between modified molecular sieves and fibers is weak, which limits the performance of composite materials.

Method used

By selectively oxidizing pulp fibers to convert -OH to -COOH, and then impregnating them in an aqueous solution of aluminum and alkali with a silicon source solution, a type A molecular sieve is synthesized in one step via a hydrothermal method, thus preparing a high-load molecular sieve/pulp fiber composite material.

Benefits of technology

The loading and uniformity of molecular sieves on pulp fibers were significantly improved, enhancing the stability of the composite material. Highly sensitive water-sensitive test paper was prepared through modification treatment.

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Abstract

本发明公开了一种高负载量的分子筛 / 纸浆纤维复合材料及其制备方法和应用。包括以下步骤:(1)对纸浆纤维进行选择性氧化处理,将‑OH转化为‑COOH;所述选择性氧化处理的药剂包括氧化性含氯化合物,其有效氯用量为0.6~3.0mmol / g绝干纤维;(2)将处理后的纸浆纤维在铝源和碱的水溶液中浸渍,再向其中加入硅源溶液,搅拌后进行陈化和晶化处理,制得高负载量的分子筛 / 纸浆纤维复合材料。该复合材料可以在水敏试纸中的应用,制备的水敏试纸有较高的灵敏度,优于市售试纸,可应用于实验教学、干燥食品包装中的水分指示、环境中水分含量的快速判断等方面。
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