一种用于环境保护的重金属土壤钝化修复方法

By coating zero-valent iron onto the surface of biomass activated carbon with FeNi@TA-AC composite material and introducing tannic acid modification to form a core-shell structure, multiple needs for heavy metal adsorption, reduction and stabilization are met, achieving efficient heavy metal soil remediation effect, and possessing stability and environmental friendliness.

CN120362240BActive Publication Date: 2026-07-17INNER MONGOLIA NO 3 GEOLOGICAL & MINERAL EXPLORATION & DEV CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INNER MONGOLIA NO 3 GEOLOGICAL & MINERAL EXPLORATION & DEV CO LTD
Filing Date
2025-05-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies cannot simultaneously meet the multiple requirements of heavy metal adsorption, reduction and stabilization. Conventional biochar is prone to desorption under acidic conditions, and zero-valent iron nanoparticles are easily oxidized in soil environments and pose a risk of secondary pollution.

Method used

The FeNi@TA-AC composite material is used to coat the surface of biomass activated carbon with zero-valent iron and introduce tannic acid to form a core-shell structure. This, combined with the porous structure and functional groups, synergistically enhances the adsorption and reduction capacity of heavy metals. Furthermore, the aggregation of zero-valent iron is prevented by Ni-catalyzed electron transfer and steric hindrance.

Benefits of technology

It achieves efficient passivation of heavy metals, improves the stability and remediation effect of materials, reduces the content of available heavy metals in soil, and can be recycled and reused through magnetic separation, thus having green and environmentally friendly advantages.

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Abstract

本发明公开了一种用于环境保护的重金属土壤钝化修复方法,属于土壤修复技术领域。针对现有生物炭吸附能力不足及零价铁易氧化团聚的技术缺陷,提出以FeNi@TA‑AC复合材料为核心的多机制协同修复方案。本发明在零价铁的表面包覆多孔活性炭,形成核壳结构,碳层作为物理屏障隔绝氧气和水分,防止零价铁氧化,活性炭的高比表面积与零价铁的高吸附性协同去除重金属;通过单宁酸改性生物炭表面,单宁酸通过多酚羟基锚定活性炭,其醌基作为电子中介体加速重金属还原;Fe‑Ni双金属通过晶格畸变降低表面能,利用电势差促进电子传递。本发明制备的复合材料对Pb、Cd、As具有明显的钝化效率,可以通过磁选法回收后循环使用,提高了材料利用率,具有绿色环保的优势。
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