一种高阻隔阻燃食品包装膜及其制备方法

A high-barrier, flame-retardant food packaging film was prepared by chemically bonding modified DOPO, crosslinking and blending a flexibility agent with melamine resin and polyvinyl alcohol. This solved the problems of flame retardant degradation and poor compatibility in existing technologies, achieving a combination of high barrier properties, flame retardancy, and flexibility, and avoiding the migration and precipitation of plasticizers.

CN120365676BActive Publication Date: 2026-07-17YANGZHOU HUAYU CO PACKAGING LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
YANGZHOU HUAYU CO PACKAGING LTD
Filing Date
2025-06-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

When improving the flame retardancy and barrier properties of existing food packaging films, the dense structure of the polymer matrix is ​​easily damaged, resulting in a decrease in barrier performance. Furthermore, the flame retardant has poor compatibility with the matrix, affecting the uniformity and strength of the film. At the same time, the addition of physical plasticizers can lead to migration and precipitation problems.

Method used

By employing a chemical bonding modification method, highly efficient and environmentally friendly DOPO flame retardant, long-chain fatty acid flexibility agent, melamine resin, and polyvinyl alcohol are crosslinked and blended to form a high-barrier flame-retardant food packaging film. DOPO provides flame retardancy, melamine resin provides rigidity and flexibility, long-chain fatty acids improve brittleness, and the PVA matrix provides gas barrier properties.

Benefits of technology

It achieves a combination of high barrier properties, halogen-free flame retardancy, good flexibility and mechanical strength, avoiding the problems of decreased barrier properties and material embrittlement in traditional methods, and also preventing plasticizer migration and precipitation, thus improving the stability and safety of packaging films.

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Abstract

本发明属于功能膜材料技术领域,具体地,涉及一种高阻隔阻燃食品包装膜及其制备方法,将聚乙烯醇溶于去离子水溶液中,并用盐酸溶液调节pH值至5,再加入部分柔软阻燃改性三聚氰胺树脂,95℃水浴加热,搅拌至完全溶解,得到部分柔软阻燃改性三聚氰胺树脂交联的聚乙烯醇共混溶液,涂布,干燥,得到高阻隔阻燃食品包装膜;本发明提供的高阻隔阻燃食品包装膜及其制备方法,通将高效环保的DOPO阻燃剂、长链脂肪酸柔韧剂与三聚氰胺树脂进行化学键合改性,再与聚乙烯醇基体交联共混,成功克服了阻燃剂添加导致阻隔性下降和材料脆化的行业难题。所制备的薄膜具有优异的氧气和水蒸气阻隔性能、高效稳定的无卤阻燃性能、良好的柔韧性和力学强度。
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