化合物硼酸钾铷钡和硼酸钾铷钡双折射晶体及其制备方法和用途

By synthesizing the compound potassium rubidium barium borate KxRb(2-x)BaB6O11 (x=0.7-1) crystal, the problems of insufficient transmittance and difficult processing of existing birefringent crystals in the deep ultraviolet region were solved, and high transmittance and large birefringence in the deep ultraviolet-infrared band were achieved, which is suitable for optical device applications.

CN120398080BActive Publication Date: 2026-07-17XINJIANG TECH INST OF PHYSICS & CHEM CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XINJIANG TECH INST OF PHYSICS & CHEM CHINESE ACAD OF SCI
Filing Date
2025-05-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing birefringent crystal materials have insufficient transmittance in the deep ultraviolet region, are difficult to process, and have poor chemical stability, making it difficult to meet the needs of optical devices.

Method used

Potassium rubidium barium borate KxRb(2-x)BaB6O11 (x=0.7-1) was synthesized by solid-state reaction and high-temperature melt method. The crystal belongs to the orthorhombic crystal system with space group Pnma. By controlling the reaction conditions, potassium rubidium barium borate birefringent crystals with high birefringence and wide transmission range were obtained.

Benefits of technology

It achieves high transmittance and high birefringence in the deep ultraviolet-infrared band. The crystal is easy to grow and process, and is suitable for optical devices such as Glan prisms and Wollaston prisms. It also has good chemical stability.

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Abstract

本发明涉及一种化合物硼酸钾铷钡和硼酸钾铷钡双折射晶体及其制备方法和用途。该化合物的化学式为KxRb(2‑x)BaB6O11,其中x=0.7‑1,分子量为502.74‑517.61,采用固相反应法合成;该晶体的化学式为KxRb(2‑x)BaB6O11,其中x=0.7‑1,分子量为502.74‑517.61,属于正交晶系,空间群是Pnma,晶胞参数为a=15.1923(9)Å,b=7.6510(5)Å,c=8.7527(5)Å,Z=4,V=1017.38(11)Å3,采用高温熔液法制备;该晶体用于深紫外‑红外波段,为双轴晶体,其透过范围为200 nm‑3500 nm,双折射率为0.08(546 nm)。在光学和通讯领域有重要应用,可用于制作偏振分束棱镜,相位延迟器件和电光调制器件。
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