一种乙烯氧氯化催化剂及其制备方法、乙烯氧氯化制备1,2-二氯乙烷的方法

By using a composite support consisting of γ-Al2O3 and Y-type molecular sieves to form an ethylene oxychlorination catalyst, and loading copper and auxiliary elements, the problem of pressurization required by existing catalysts was solved. This achieved efficient hydrogen chloride conversion and selectivity for 1,2-dichloroethane under normal pressure, reducing equipment requirements and byproduct generation.

CN120421025BActive Publication Date: 2026-07-17QINGDAO UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
QINGDAO UNIV OF SCI & TECH
Filing Date
2025-04-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing ethylene oxychlorination catalysts require pressurized conditions to achieve high conversion rates of hydrogen chloride and high selectivity for 1,2-dichloroethane, which presents high equipment requirements and safety risks. Furthermore, traditional catalysts are prone to generating byproducts.

Method used

A composite support consisting of γ-Al2O3 and Y-type molecular sieves was used to load copper and auxiliary elements to form an ethylene oxychlorination catalyst. By improving the catalyst structure and materials, high conversion of hydrogen chloride and high selectivity of 1,2-dichloroethane were achieved under normal pressure.

Benefits of technology

Achieving a hydrogen chloride conversion rate of over 99% and a 1,2-dichloroethane selectivity of over 98% under normal pressure reduces equipment requirements and safety risks, and minimizes byproduct generation.

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Abstract

本发明涉及催化剂制备技术领域,提供了一种乙烯氧氯化催化剂及其制备方法、乙烯氧氯化制备1,2‑二氯乙烷的方法。本发明以γ‑Al2O3和Y型分子筛作为复合载体,使得复合载体具有独特的孔道结构、可调的酸碱性和优良的热稳定性,来抵抗积碳的形成。复合载体独特的孔道结构使活性组分能更均匀地分布于复合载体上,降低了活性成分的团聚,增强了活性组分的有效利用率,保持反应的高活性。本发明的乙烯氧氯化催化剂以γ‑Al2O3和Y型分子筛作为复合载体,结合活性组分铜元素,使得乙烯氧氯化催化剂在常压下也能够实现乙烯的氧氯化,且氯化氢转化率高,1,2‑二氯乙烷的选择性高。
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