一种正性光刻胶组合物及其应用

By developing a positive photoresist composition containing polysulfide polymers, the problems of negative photolithography properties of metal oxide cluster photoresists and low sensitivity of polymer photoresists have been solved, achieving high-sensitivity and high-resolution photolithography effects suitable for EUV lithography processes in integrated circuits.

CN120447304BActive Publication Date: 2026-07-17NANKAI UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANKAI UNIV
Filing Date
2025-06-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Metal oxide cluster photoresists exhibit negative photolithography properties during the photolithography process, making it difficult to meet the requirements of EUV photolithography for integrated circuits. Furthermore, polymer photoresists have low sensitivity in the extreme ultraviolet region.

Method used

A positive photoresist composition was developed, comprising a polysulfide polymer compound and a photoresist solvent, which forms a cross-linked network structure through a thiol olefin click reaction, and utilizes the high light absorption and post-exposure fracture characteristics of antimony to achieve positive photolithography.

Benefits of technology

It achieves high sensitivity and high resolution lithography effects, and is suitable for electron beam, 248nm lithography, 193nm lithography and extreme ultraviolet lithography, meeting the lithography process requirements of integrated circuits.

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Abstract

本发明公开了一种正性光刻胶组合物及其应用,所述正性光刻胶组合物包含有聚硫醚高分子化合物以及光刻胶溶剂。所述聚硫醚高分子化合物包含如下结构:所述聚硫醚高分子化合物由9摩尔份数的多核锑单元、7.0~9.0摩尔份数的二元硫醇、1.0~0摩尔份数的多元硫醇、光引发剂、溶剂,在室温的空气氛围经紫外光引发的硫醇烯点击反应进行聚合,反应后将溶剂旋蒸干净后得到。所述聚硫醚高分子化合物的质量占所述正性光刻胶组合物总质量的1wt%~20wt%,其余为光刻胶溶剂。所述正性光刻胶组合物可以在电子束和极紫外光(EUV)曝光下实现正性光刻效果,在较低电子束曝光剂量下达到较高分辨率,并可以在较宽的32.9‑217.4mJ / cm2极紫外光曝光剂量下达到25nm的分辨率。
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