一种重金属污泥的无害化处置及资源化利用工艺

By preparing a magnetic heavy metal adsorbent and combining it with celery seeds and illite to form a heavy metal adsorption colloidal solution, the problems of secondary pollution and low resource utilization efficiency in phosphorus recovery from sludge incineration ash were solved, achieving efficient and environmentally friendly phosphorus resource recovery and sludge resource utilization.

CN120483476BActive Publication Date: 2026-07-17SHANDONG HUIZE ENVIRONMENTAL PROTECTION NEW MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG HUIZE ENVIRONMENTAL PROTECTION NEW MATERIALS CO LTD
Filing Date
2025-05-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for recovering phosphorus from sludge incineration ash suffer from problems such as secondary pollution from chemical reagents, high processing costs, and cumbersome processes. Furthermore, the adsorption rate of ordinary adsorbents is insufficient, making it difficult to achieve efficient resource utilization of sludge.

Method used

By preparing a magnetic heavy metal adsorbent, nano-magnetic particles were obtained by reflux reaction of acetylacetone iron, 1,2-dodecanediol, anhydrous ethanol, oleic acid oleylamine and dibenzyl ether. These particles were then combined with celery seeds and illite to form a heavy metal adsorption colloidal solution. The pH value was adjusted using a single reagent to achieve efficient adsorption of heavy metals and gradual precipitation of phosphorus.

Benefits of technology

It achieves harmless disposal and resource utilization, avoids secondary pollution from chemical reagents, improves the resource utilization efficiency of sludge, simplifies the process flow, and produces products including lithium iron phosphate and ammonium chloride fertilizers, which have the potential for high purity and efficient resource utilization.

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Abstract

本发明属于资源回收利用技术领域,具体涉及一种重金属污泥的无害化处置及资源化利用工艺。包括以下步骤:磁性胶体溶液和重金属吸附胶体溶液的制备;重金属吸附胶体与PAA互穿包覆磁性颗粒;污泥燃烧棒的制备及其焚烧灰的处理。本发明通过将焚烧灰进行酸浸后加入磁性重金属吸附剂除去重金属离子,避免影响后续资源化产物的纯度以及环保性能,然后再通过依次调节pH,逐步析出含磷浸出液中的有效成分,其中磷酸铁能够进一步加工成磷酸铁锂,应用于制备电池材料中,而后续加入氨水使pH为中性后,溶液中还含有Ca、Mg、K、P、Na元素和氯化铵,稀释后能够应用于强耐氯植物的肥料。
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