一种磷石膏的处理方法

By using a method to prepare microcrystalline glass panels, the problems of high leakage risk and complex process in phosphogypsum treatment have been solved, realizing efficient and safe resource utilization of phosphogypsum and producing high-strength microcrystalline glass panels for building decoration.

CN120483530BActive Publication Date: 2026-07-17湖南新万润新型材料有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
湖南新万润新型材料有限公司
Filing Date
2025-05-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for treating phosphogypsum present problems such as high leakage risk and complex processes, making it difficult to utilize phosphogypsum efficiently and safely, leading to environmental pollution.

Method used

The desulfurized glass melt is prepared and microcrystallized to obtain microcrystalline glass plates through mixing and melting of the ingredients. The process is simple and eliminates the pretreatment step. It uses phosphogypsum, quartz sand, soda ash, sodium fluorosilicate and feldspar as raw materials, and adds antimony powder and sodium nitrate as additives. The melting temperature and cooling rate are controlled, and sulfur-containing flue gas is treated by segmented spraying of ammonia.

Benefits of technology

This method enables the efficient and safe utilization of phosphogypsum to produce high-strength microcrystalline glass panels, reducing environmental pollution. The process is simple, and the microcrystalline glass panels can be used for building decoration, thus promoting the resource utilization of phosphogypsum.

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Abstract

本发明提供了一种磷石膏的处理方法,属于固体废弃物的回收与应用技术领域。该方法包括步骤:提供配料的组分包括:磷石膏40~50%、石英砂20~30%、纯碱6~10%、氟硅酸钠6~10%以及长石10~15%。将配料于1400~1600℃下的熔化处理,得脱硫玻璃液和含硫烟气。对脱硫玻璃液依次进行冷却处理、成型处理以及微晶化处理,得微晶玻璃板。该方法省去了常规对磷石膏处理工艺中对磷石膏进行预处理的操作,工艺流程简洁;且高效利用了磷石膏,得到的微晶玻璃板的抗弯强度高达89MPa,该微晶玻璃板可被广泛应用于建筑装饰中。推进了磷石膏“变废为宝”的进程,为磷石膏高效资源化利用作出积极贡献。
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