基于有机-无机杂化包覆层的正极材料、制备方法与应用

By employing a three-layer structure of organic-inorganic hybrid coating on the surface of the cathode material, mechanical stress caused by thermal expansion is alleviated, electrolyte corrosion is neutralized, and microcrack self-repair is achieved. This solves the stability and transport efficiency problems of existing cathode materials under high-temperature environments and improves the performance of lithium-ion batteries.

CN120497317BActive Publication Date: 2026-07-17JINGMEN GEM NEW MATERIAL CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JINGMEN GEM NEW MATERIAL CO LTD
Filing Date
2025-06-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing cathode materials are prone to structural changes during charging and discharging, leading to rapid capacity decay. They are also prone to thermal decomposition reactions at high temperatures, reducing battery safety and electrochemical performance. Furthermore, existing coatings cannot balance lifespan and lithium-ion transport efficiency.

Method used

A cathode material based on an organic-inorganic hybrid coating layer is adopted, which includes a three-layer structure of a core, a buffer layer and a dopamine-modified dielectric layer. The uniform coating of the dopamine-modified dielectric layer is achieved by fluidized bed chemical vapor deposition, which buffers the difference in thermal expansion coefficient, neutralizes the acid corrosion of the electrolyte, improves conductivity and realizes dynamic self-repair of microcracks.

Benefits of technology

It improves the stability and lifespan of the battery under high-temperature conditions, optimizes the lithium-ion transport channel, reduces interface impedance, improves the charge and discharge efficiency and rate performance of the battery, and extends the lifespan of the lithium-ion battery.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure SMS_2
    Figure SMS_2
  • Figure SMS_3
    Figure SMS_3
Patent Text Reader

Abstract

本发明涉及一种基于有机‑无机杂化包覆层的正极材料、制备方法与应用,所述正极材料包括内核、包覆所述内核的缓冲层以及包覆所述缓冲层的多巴胺修饰电介质层;所述内核包括三元正极材料;所述缓冲层包括非晶态Al2O3层。所述缓冲层能够缓冲内核与多巴胺修饰电介质层的热膨胀系数差异;所述多巴胺修饰电介质层兼具离子导电性与动态自修复功能,能够有效中和电解液的酸性腐蚀,提升导电性的同时降低界面阻抗;本发明提供的基于有机‑无机杂化包覆层的正极材料具有较高的倍率性能和界面稳定性,具有较长的使用寿命,在高温下具有稳定的工况,因此,包括本发明提供正极材料的电池具有优良的电化学性能。
Need to check novelty before this filing date? Find Prior Art