一种基于动态网络重构制备热固性聚酰亚胺复合材料的方法

By employing dynamic network reconstruction and temperature-driven wetting techniques, the processing difficulty and interfacial compatibility issues of thermosetting polyimide composites have been resolved, enabling the low-temperature preparation of high-strength, chemically resistant composite materials suitable for aerospace and other fields.

CN120535792BActive Publication Date: 2026-07-17HARBIN INST OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HARBIN INST OF TECH
Filing Date
2025-06-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing thermosetting polyimide composite materials suffer from problems such as high processing difficulty, high energy consumption, high material brittleness, and poor interfacial compatibility with carbon fibers during preparation.

Method used

A dynamic network reconstruction method was adopted to achieve reversible dissociation and reconstruction of polymer networks through heating/cooling cycles. By combining temperature-driven wetting and pressure-temperature synergistic processes, a low-temperature sol state was prepared to wet carbon fibers, which then formed a high-temperature stable covalent network.

Benefits of technology

It reduces processing temperature and equipment energy consumption, improves material toughness and interfacial strength, is suitable for low-cost mass production of carbon fiber prepregs, and has excellent chemical corrosion resistance.

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Abstract

一种基于动态网络重构制备热固性聚酰亚胺复合材料的方法,属于功能材料技术领域。所述方法为:在冰水浴条件下,将二胺单体分散在非质子极性溶剂中,加入二酐单体,搅拌反应,即得聚酰胺酸溶液;向前述溶液中加入三胺交联剂5‑30min后,溶液变为凝胶态;将碳纤维织物裁剪后铺放在预备好的容器中,将凝胶放在碳纤维织物上并置于120℃真空烘箱中,此时凝胶逐渐变化为溶胶将CF浸渍,随后进行抽真空,直至溶剂蒸发,生成TCPAA / CF复合材料;将其置于热压机中,预压冷却后,置于马弗炉中,在250℃保温1h,300℃保温1 h即可。该方法通过步骤三的加热 / 冷却循环实现聚合物网络的可逆解离与重构,制备出的薄膜热稳定性好,解决了传统TCPI凝胶体系对CF浸润性差的技术难题。
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