基于等离子体的硫化砷渣贫化处理铜渣的方法

By using a plasma torch to excite the reaction between arsenic sulfide slag and copper slag to generate highly active S2-, the problems of smoke and dust and insufficient sulfidation in copper slag recycling are solved. This enables the efficient recovery of valuable metals such as copper, lead, and zinc, as well as the fixation of arsenic, thereby improving resource utilization and environmental safety.

CN120536738BActive Publication Date: 2026-07-17CENT SOUTH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2025-05-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing copper slag recycling processes suffer from the generation of harmful fumes and insufficient sulfidation reduction, resulting in low recovery efficiency of valuable metals such as copper, lead, and zinc. Furthermore, the long-term storage of sulfided arsenic slag pollutes the environment.

Method used

A plasma torch is used to excite arsenic sulfide slag and copper slag to undergo a sulfidation reaction in a depletion furnace, generating highly active S2-, which reacts with valuable metals in the copper slag. The valuable metals are then fixed in the metal matte phase through a depletion-slow cooling process. Using arsenic sulfide slag as a depletion agent eliminates the need for additional reducing agents.

Benefits of technology

It achieves efficient recovery of valuable metals such as copper, lead, and zinc. The arsenic element in the arsenic sulfide slag is fixed in the slag phase, reducing the generation of harmful dust, improving resource recovery rate and environmental safety, and meeting the requirements of green and clean production.

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Abstract

本发明提供了一种基于等离子体的硫化砷渣贫化处理铜渣的方法,该方法包括:在等离子体炬作用下,将硫化砷渣和铜渣引入至贫化炉中进行硫化反应,得到热态渣,并将热态渣进行缓冷,得到缓冷渣;缓冷渣包括界限分明的金属锍相和炉渣相,硫化砷渣中的砷元素固定于炉渣相中;等离子体炬以N2与CO、CH4中至少一种作为工作介质;硫化砷渣的含水率≯1.5%,平均粒径≮200目;铜渣与硫化砷渣的用量质量比为100:3‑6。本发明提供的方法将高活性S2‑与铜渣中有价金属进行硫化反应,能够通过等离子体炬的喷吹搅动热贫化炉中的物料,促进硫化砷渣和铜渣两种物料均匀混合,从而起到加速强化物料硫化的作用,显著缩短硫化反应时间。
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