一种超高镍三元正极材料及其制备方法和应用

By employing a wet process of Sr and La co-doping and wet coating of lithium lanthanum titanate and Li3PO4, combined with boric acid surface modification, the structural instability and insufficient electrical performance of ultra-high nickel cathode materials were solved, achieving high cycle stability and excellent conductivity of the material.

CN120581567BActive Publication Date: 2026-07-17JIANGSU YILI TECH CO LTD
View PDF 2 Cites 0 Cited by

Patent Information

Application Number
CN202510750590.8
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-06-05
Publication Date
2026-07-17
Estimated Expiration
2045-06-05

AI Technical Summary

Technical Problem

Existing ultra-high nickel cathode materials suffer from problems such as easy particle crushing due to the formation of surface rock salt phase, dissolution of transition metals, deterioration of electrode-electrolyte interface, poor cycle performance and thermal stability, and the mechanical degradation problem has not been solved.

Method used

The core material is doped using a wet process with Sr and La co-doping, combined with wet coating of lithium lanthanum titanate and Li3PO4, and further modified with boric acid and/or boron oxide to form a core and coating layer structure, thereby improving the structural stability and electrical properties of the material.

Benefits of technology

Significant improvements in the structural stability and electrical conductivity of ultra-high nickel ternary cathode materials have been achieved, exhibiting excellent cycle performance and electrical performance, thus solving the problem of insufficient material stability and electrical performance in existing technologies.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN120581567B_ABST
    Figure CN120581567B_ABST
Patent Text Reader

Abstract

本发明提供了一种超高镍三元正极材料及其制备方法和应用。所述制备方法包括:提供前驱体材料,其为镍摩尔比例90%以上的镍钴锰氢氧化物;对所述前驱体材料进行湿法掺杂,掺杂元素包括Sr和La,得到第一中间体材料;将所述第一中间体材料与锂源混合后进行第一烧结,得到第二中间体材料;采用第一包覆材料对所述第二中间体材料进行湿法包覆,并进行第二烧结形成第三中间体材料,所述第一包覆材料包括钛酸镧锂和Li3PO4;采用第二包覆材料对所述第三中间体材料进行包覆,并进行第三烧结,得到超高镍三元正极材料,第二包覆材料包括硼酸和 / 或氧化硼。本发明制备的超高镍三元正极材料具有优异的结构稳定性,展现良好的材料电导率和较高循环性,电性能良好。
Need to check novelty before this filing date? Find Prior Art

Citation Information

Patent Citations

  • Lithium ion battery positive electrode material, preparation method thereof and lithium ion battery

    CN116632240A

  • High-nickel ternary positive electrode material as well as preparation method and application thereof

    CN117374250A