一种利用镁基氧化物循环分解氯化铵制备盐酸和氨水的方法

Hydrochloric acid and ammonia are prepared by the cyclic reaction of magnesium-based oxides and ammonium chloride, which solves the problems of high energy consumption and low resource utilization in the treatment of high-concentration ammonium chloride wastewater, and realizes efficient and environmentally friendly resource recycling.

CN120589688BActive Publication Date: 2026-07-17HANGZHOU BAOTOU RARE EARTH TECH DEV CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HANGZHOU BAOTOU RARE EARTH TECH DEV CO LTD
Filing Date
2025-06-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for treating high-concentration ammonium chloride wastewater are energy-intensive, and using ammonium chloride as fertilizer can lead to soil compaction. Hydrochloric acid and ammonia water have low recycling rates, and the generated anhydrous calcium chloride is difficult to sell. Chemical precipitation methods have simple equipment but are costly and the products are difficult to sell.

Method used

Magnesium-based oxides are mixed with ammonium chloride and heated to produce ammonia and hydrogen chloride gas. Ammonia water and hydrochloric acid are then prepared by water absorption, and the magnesium-based oxides are recycled to improve reaction efficiency and product yield.

Benefits of technology

It achieves efficient decomposition of ammonium chloride to produce hydrochloric acid and ammonia for rare earth smelting, thereby improving resource utilization, reducing energy consumption and environmental pollution.

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Abstract

本发明公开了一种利用镁基氧化物循环分解氯化铵制备盐酸和氨水的方法,属于资源综合利用领域,其步骤为将含水量为氯化铵与镁基氧化物按照重量比为在混料机中混合,得到混合物;将混合物加入反应器,加热反应,获得氨气和第一反应物,氨气用水吸收获得氨水;将第一反应物在反应器中升高反应温度,再次反应,获得氯化氢气体和第二反应物;将第二反应物在气流粉碎机中破碎,再与新的氯化铵进行循环反应。本发明可循环利用镁基氧化物、氢氧化物分解氯化铵,制备盐酸和氨水,其具有分解转化率高、盐酸和氨水可循环用于稀土冶炼分离工序,具有很好的环境效益。
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