一种多孔钠离子电池焦磷酸磷酸铁钠正极材料的制备方法

By constructing a porous NFPP cathode material using a two-step etching method, the problems of low porosity and poor conductivity of traditional NFPP materials are solved, achieving efficient ion diffusion and improved electrochemical performance, making it suitable for sodium-ion batteries.

CN120622438BActive Publication Date: 2026-07-17HUBEI XINGFA CHEM GRP CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUBEI XINGFA CHEM GRP CO LTD
Filing Date
2025-06-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional sodium iron phosphate pyrophosphate (NFPP) cathode materials suffer from low porosity, poor conductivity, and poor ion diffusion, resulting in insufficient electrochemical performance.

Method used

A two-step etching method was adopted. First, the carbon layer was initially opened and the SiO2 template surface was activated by the IPA-HF system. Then, deep etching was carried out in the HF solution containing sodium citrate to construct a through and uniform porous structure. Free carbon was removed by centrifugal cleaning.

Benefits of technology

It significantly improves the specific surface area and ion diffusion performance of NFPP cathode materials, enhances electrochemical performance and cycle stability, and increases the compaction density and mechanical strength of the materials.

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Abstract

本发明涉及一种多孔钠离子电池焦磷酸磷酸铁钠正极材料的制备方法,属于钠离子电池正极材料技术领域。该方法包括前驱体浆料制备、砂磨、喷雾干燥、低温热处理、表面活化、双阶段刻蚀、高温煅烧等步骤。其中,采用异丙醇‑氢氟酸体系对前驱体进行第一阶段刻蚀以打开碳包覆层,提高后续刻蚀液的渗透性;随后采用氢氟酸‑柠檬酸钠体系在加热条件下进行第二阶段深层刻蚀,有效去除二氧化硅模板,形成贯通式多孔结构。所得正极材料具备良好的孔隙结构和导电网络,有利于电解液浸润和钠离子扩散通道的构建,从而提升其倍率性能与循环稳定性。本发明制备方法工艺简便,适用于高性能钠离子电池正极材料的规模化制备。
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