一种迅速获得高磁热性能的La-Fe-Co-Si稀土磁制冷合金制备方法

By incorporating BN nanosheets into La-Fe-Co-Si alloys and utilizing selective laser melting and annealing, the problems of long heat treatment time and poor formability of La-Fe-Co-Si alloys were solved, and the efficient preparation of rare earth magnetic refrigeration alloys with high magnetocaloric performance was achieved.

CN120624875BActive Publication Date: 2026-07-17SHENYANG LIGONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHENYANG LIGONG UNIV
Filing Date
2025-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, La-Fe-Co-Si rare earth magnetic refrigeration alloys have long high-temperature heat treatment times, poor formability, and low mechanical properties, making them difficult to apply in large quantities.

Method used

Selective laser melting technology was used to incorporate BN nanosheets into La-Fe-Co-Si alloys. Combined with annealing and air cooling heat treatment, the formation of the magnetocaloric phase La(Fe,Co,Si)13 was promoted, the heat treatment time was shortened, and the mechanical strength and magnetocaloric properties were improved.

Benefits of technology

The annealing time of La-Fe-Co-Si alloy is significantly shortened to 10-20 minutes, improving magnetocaloric properties and mechanical strength, enhancing the alloy's formability, and making it suitable for magnetic refrigeration applications.

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Abstract

本发明涉及合金制备技术领域,且特别涉及一种迅速获得高磁热性能的La‑Fe‑Co‑Si稀土磁制冷合金制备方法。在氩气保护气氛下,采用选区激光熔化的3D打印技术将BN纳米片掺入La‑Fe‑Co‑Si合金,后续通过短时退火+空冷热处理获得高磁热性能的La‑Fe‑Co‑Si稀土磁制冷合金。利用选区激光熔化的方法向合金中掺入BN纳米片以引入B元素,促进磁热相相的形成,降低第二相含量,进一步细化组织,为后续La(Fe,Co,Si)13的形成提供形核位点,缩短热处理时间,提高力学强度,降低磁滞后,提高磁热性能,增强合金成型性,从而有效解决了La‑Fe‑Co‑Si磁制冷合金高温热处理时间长、成型难的问题。
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