一种2.5维锑掺杂二氧化锡 / 聚氨酯-钌钛混合氧化物 / 聚合物温度响应型电催化氧化电极及制备方法

By utilizing temperature response to regulate the binding state of the sub-electrode in a 2.5-dimensional electrocatalytic oxidation electrode, the problems of strong magnetic binding and insufficient material flexibility in existing electrodes are solved, and dynamic adaptive adjustment of electrode composition and structure and efficient organic matter degradation are achieved.

CN120736637BActive Publication Date: 2026-07-17SHAANXI UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHAANXI UNIV OF SCI & TECH
Filing Date
2025-07-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing 2.5D electrocatalytic oxidation electrodes rely on strong magnetic bonding, have insufficient material flexibility, high interfacial resistance, and are difficult to load and unload flexibly through temperature changes. Furthermore, the traditional electrode composition/structure adjustment is limited and cannot adapt to complex and variable wastewater composition.

Method used

By loading antimony-doped tin dioxide onto molecular sieve particles and coating them with a polyurethane thermal expansion layer to form a secondary electrode, and bonding ruthenium-titanium mixed oxide onto a porous titanium matrix and spraying a polymer layer to form a primary electrode, the bonding state of the secondary electrode is controlled by temperature, thereby achieving stable bonding and dynamic adaptive adjustment between the primary electrode and the particle secondary electrode.

Benefits of technology

It achieves dynamic adaptive adjustment of electrode composition and structure, improves catalytic ability and stability, is suitable for complex wastewater treatment, and has higher organic matter degradation and conversion efficiency and in-situ material recovery characteristics.

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Abstract

本发明公开了一种2.5维锑掺杂二氧化锡 / 聚氨酯‑钌钛混合氧化物 / 聚合物温度响应型电催化氧化电极及制备方法,属于电催化氧化电极制备技术领域,在分子筛颗粒上通过水解缩聚反应和退火的方式负载无定形的锑掺杂二氧化锡,之后在表面涂覆聚氨酯形成的热膨胀层,得到副电极颗粒;在多孔钛基体上键合钌钛混合氧化物层,之后喷涂N‑异丙基丙烯酰胺‑丙烯酸共聚物形成的聚合物层,得到主电极;将副电极颗粒悬浮在主电极上,之后静置,主电极靠近副电极颗粒的表面孔道直径缩小,副电极颗粒靠近主电极一端的热膨胀层受热膨胀,最后锁紧在主电极的孔道内得到该温度响应型电催化氧化电极,使主电极与颗粒副电极充分且稳定地结合,并赋予电极组成结构动态自适应调整的能力,克服传统电极组成 / 结构调节局限,兼具性能原位可调和材料原位回收特性。
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