一种强韧全生物基聚乳酸 / 聚酰胺复合材料及其制备方法

By preparing core-shell amide modified materials to improve the compatibility and interfacial tension of polylactic acid/polyamide blends, the problems of brittleness and poor impact resistance of polylactic acid materials were solved, enabling the application of high-performance composite materials.

CN120737568BActive Publication Date: 2026-07-17TIANJIN UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TIANJIN UNIV
Filing Date
2025-07-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Polylactic acid (PLA) materials suffer from brittleness, low elongation at break, and poor impact resistance in engineering applications, making it difficult to meet the requirements of automotive parts and other fields. Existing blending modification methods suffer from phase separation and low impact strength.

Method used

Core-shell amide modified materials were prepared by using amino nanoparticle reactive-filled functional elastomer copolymers. By forming a micro-core-shell structure in situ, the compatibility and interfacial tension of the polylactic acid/polyamide blend system were improved. Hydrolysis stabilizers and antioxidants were added to improve processing stability, and chain extenders were added to improve melt strength.

Benefits of technology

The prepared strong and tough polylactic acid/polyamide composite material has excellent tensile strength, elongation at break and impact resistance. The tensile strength reaches 60-75MPa, the elongation at break is 200-400%, and the notched impact strength can reach up to 50kJ/m2. It is suitable for engineering plastics fields such as automotive parts.

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Abstract

本发明公开了一种强韧全生物基聚乳酸 / 聚酰胺复合材料及其制备方法,属于高分子复合材料制备技术领域。本发明的强韧聚乳酸 / 聚酰胺复合材料中包括聚乳酸、生物基聚酰胺、核壳酰胺改性料、水解稳定剂、抗氧剂和扩链剂;所述核壳酰胺改性料通过氨基纳米粒子填充功能弹性体共聚物制得。基于氨基纳米粒子反应性填充功能弹性体共聚物所形成的核壳酰胺改性料具有原位形成的微观核壳结构以及大量酰胺键,这同时增加了共混物体系分子链间氢键数目,改善了共混物材料微观分子链间缠结以及分子间作用力,因而改善了体系相容性并增强了材料对外部应力以及能量的吸收,在材料受力变形时产生了更加显著的塑性变形,赋予材料更好的机械性能。
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