一种耐压缩变形的橡胶密封件及其制备方法

By combining graphene-modified and aldehyde-terminated polybutadiene rubber with piperazine to form an imine-bonded elastomer, and then using gradient temperature vulcanization treatment, the problem of deformation of rubber seals under high stress and high temperature is solved, improving their compression resistance and tensile strength, and ensuring the stability of the sealing function.

CN120757888BActive Publication Date: 2026-07-17XUZHOU BAOXIN SEAL CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XUZHOU BAOXIN SEAL CO LTD
Filing Date
2025-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Rubber seals are prone to slippage or fracture under high stress and high temperature conditions, resulting in permanent deformation, loss of cushioning and self-adaptive capabilities, reduced fatigue resistance, and impaired sealing function.

Method used

Polybutadiene rubber with graphene-modified pretreatment and aldehyde-terminated ends is reacted with piperazine to form an elastomer containing imine bonds. Combined with gradient temperature vulcanization treatment, the crosslinking density and dynamic crosslinking characteristics of the rubber seal are increased. The thermal conductivity of graphene is used to improve the uniformity of vulcanization and annealing.

Benefits of technology

It improves the resistance of rubber seals to compression set, enhances tensile strength and thermal conductivity, and ensures the stability and durability of the sealing function.

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Abstract

本发明公开了一种耐压缩变形的橡胶密封件及其制备方法,属于橡胶密封件技术领域,该涂料包括如下组分:改性石墨烯、醛基封端的聚丁二烯橡胶、哌嗪、氢化丁腈橡胶、氟橡胶、白炭黑、氟化钙,炭黑和助剂。该橡胶密封件的制备方法包括如下步骤:S1、制备改性石墨烯;S2、制备预分散母胶;S3、制备弹性体;S4、对原料进行分段混炼制备混炼胶体;S5、对混炼胶体进行分段硫化处理并退火。本发明通过醛基封端的聚丁二烯橡胶和哌嗪生成含有亚胺键的弹性体,配合石墨烯的片层结构限制橡胶分子链的不可逆滑移,利用亚胺键可发生断裂并重新形成,赋予橡胶体动态交联的特性,增加该种橡胶密封件的耐压缩永久变形性能。
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