一种两步提取铜阳极泥分银渣中铅的方法

By optimizing process parameters through a two-step leaching method and treating copper anode mud with sodium hydroxide, hydrogen peroxide, and sodium sulfide solutions to separate silver slag, the high energy consumption and environmental pollution problems of lead recovery were solved, achieving efficient and low-cost lead recovery.

CN120776120BActive Publication Date: 2026-07-17INST OF GEOGRAPHY HENAN ACAD OF SCI +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INST OF GEOGRAPHY HENAN ACAD OF SCI
Filing Date
2025-07-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for extracting lead from silver slag from copper anode mud suffer from problems such as high energy consumption, environmental pollution, high cost, complex processes, and stringent equipment requirements. Furthermore, traditional methods are difficult to achieve efficient and low-cost lead recovery.

Method used

A two-step leaching method is adopted. First, the copper anode mud is leached to separate silver residue with sodium hydroxide solution. Then, it is leached with a mixed solution of hydrogen peroxide and sodium hydroxide. Finally, the lead leaching solution is recovered with sodium sulfide solution and the alkaline leaching solution is recycled. The process parameters are optimized to achieve deep leaching of lead.

Benefits of technology

It increased the lead leaching rate to 97%, reduced reagent consumption and production costs, reduced environmental pollution, met environmental protection policy requirements, and achieved efficient lead recycling.

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Abstract

本发明公开了一种两步提取铜阳极泥分银渣中铅的方法,属于有色金属湿法冶金技术领域。本发明第一步将铜阳极泥分银渣置于氢氧化钠溶液中通过机械搅拌进行浸出,离心分离得富铅浸取液和初浸铅渣,第二步用双氧水及氢氧化钠的混合溶液对初浸铅渣做二次浸出,第三步用硫化钠溶液与富铅浸取液反应得到沉铅渣和碱性浸出液,沉铅后的碱性浸出液可循环使用。本发明可实现铜阳极泥分银渣中铅的深度提取,沉铅后的碱性浸出液可循环使用,显著降低了冶金固废处理过程中的试生产成本与环境污染。
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