Lightweight sintered brick prepared from waste felt carbon fiber and processing technology thereof
Patent Information
- Application Number
- CN202511044740.X
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2025-07-29
- Publication Date
- 2026-09-22
- Estimated Expiration
- 2045-07-29
AI Technical Summary
[0002]碳纤维毛毡是一种由碳纤维与粘结树脂结合固化后形成的隔热毡材料,被广泛应用于工业、运输业中的隔热工程中,虽然碳纤维具有着良好的力学性能与耐高温性能,可以耐受数百度温度而性质稳定,但是受限于粘结树脂的自身性质,在长期高温环境下粘结树脂会出现性能劣化,导致碳纤维毛毡强度不断下降,出现掉渣等缺陷,使其无法满足隔热工程需求,而对于废弃碳纤维毛毡直接进行废弃、填埋处理,则毫无疑问会造成巨大浪费,因此有必要针对废毛毡碳纤维再利用进行研究
[0019]本发明为了提升废毛毡碳纤维的再利用,将其作为烧结砖的原料进行了改性,由于烧结砖在制备过程中需要经历上千度的高温烧结,在该温度下,碳纤维材料往往会被空气氧化而出现性能劣化乃至消耗,因此为了避免碳纤维在烧结过程中的氧化损耗,本发明对旧碳纤维毛毡在经历破碎剪切后,对其在氮气氛围下升温至450~500℃对其表面树脂进行去除,之后降温至300℃左右将其置于空气氛围下进一步去除树脂残炭后,对其进行酸蚀氧化处理,增加其表面羟基含量,之后将其与KH550混合,经水解形成硅凝胶后,将其升温,并通入甲烷气体后,从而在碳纤维表面生成碳化硅层,碳化硅层可以对碳纤维基体有效进行保护,从而避免在高温下碳纤维的氧化,并且,由于碳纤维材料属于脊性材料,为了避免烧结砖在烧结过程中结合强度、力学强度的下降,因此本申请还在其中添加了硼泥组分,硼泥是一种在生产硼砂和硼酸过程中产生的工业固体废渣,其中含有较多的非晶态物质,将其添加至原料中,可以有效改善对碳纤维的浸润性,从而将碳纤维与烧结砖之间更好的结合在一起,提升烧结砖的抗折强度。
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Abstract
Description
Technical Field
[0001] This invention relates to the field of carbon materials technology, specifically to a lightweight sintered brick prepared from waste felt carbon fiber and its processing technology. Background Technology
[0002] Carbon fiber felt is a thermal insulation material formed by bonding and curing carbon fibers with a bonding resin. It is widely used in thermal insulation projects in industry and transportation. Although carbon fibers have good mechanical properties and high temperature resistance, and can withstand temperatures of several hundred degrees Celsius with stable properties, the properties of the bonding resin itself are limited. Under long-term high-temperature environments, the bonding resin will deteriorate, leading to a continuous decrease in the strength of the carbon fiber felt and defects such as shedding. This makes it unable to meet the requirements of thermal insulation projects. Directly discarding and landfilling waste carbon fiber felt would undoubtedly cause huge waste. Therefore, it is necessary to study the reuse of waste carbon fiber felt. Summary of the Invention
[0003] The purpose of this invention is to provide a lightweight sintered brick prepared from waste felt carbon fiber and its processing technology, so as to solve the problems raised in the prior art.
[0004] To achieve the above objectives, the present invention provides the following technical solution: a processing method for lightweight sintered bricks prepared using waste felt carbon fibers, comprising the following steps:
[0005] S1. Waste carbon fiber felt is sheared and crushed to obtain a mixture of waste carbon fiber.
[0006] S2. Under a nitrogen atmosphere, the waste carbon fiber mixture is heated to 450~500℃ and held for 25~40 min. Then, it is cooled to 300~350℃, air is introduced, and it is held for 10~15 min. After cooling to room temperature, the calcined waste carbon fiber mixture is added to clean water and ultrasonically treated to remove residual carbon powder on the surface. After separation and drying, it is added again to a mixture of concentrated sulfuric acid and concentrated nitric acid, heated to 60℃, ultrasonically vibrated for 20~40 min, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber.
[0007] S3. Add the recycled carbon fiber to anhydrous ethanol, add KH550, mix well, add deionized water, and continue to add dilute hydrochloric acid to adjust the pH of the mixture to 2.5~3.5. After ultrasonic vibration reaction for 12 hours, dry to constant weight, heat to 350~400℃ under nitrogen atmosphere and hold for 10~15 minutes, then heat to 980~1050℃, introduce methane gas, hold for 1~4 hours, and cool to room temperature to obtain modified recycled carbon fiber.
[0008] S4. After crushing and sieving coal gangue, bentonite, red mud and boron mud respectively, they are mixed with modified recycled carbon fiber to obtain dry mixture. After adding binder, a semi-wet blank is prepared. After blanking, it is placed in an environment of 20~25℃ and 85~95% relative humidity for 3~5 days to age. After sintering, a lightweight sintered brick made from waste felt carbon fiber is obtained.
[0009] Furthermore, in step S1, the particle size length of the waste carbon fiber mixture in each direction is 5~25mm.
[0010] Furthermore, in step S2, the mixed acid is a mixed acid solution of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1.
[0011] Furthermore, in step S3, the amount of each component added, by weight, is 1 part of recycled carbon fiber, 3-5 parts of anhydrous ethanol, 0.1-0.4 parts of KH550, and 0.5-1.5 parts of deionized water.
[0012] Furthermore, in step S4, the coal gangue, after being crushed, has a particle size of 1-3 mm; the bentonite, red mud, and borax mud, after being crushed, have a particle size of 0.05-0.1 mm.
[0013] Furthermore, in step S4, the contents of each component by weight are 20-35 parts coal gangue, 20-30 parts bentonite, 5-10 parts red mud, 5-10 parts boron mud and 5-15 parts modified recycled carbon fiber.
[0014] Furthermore, in step S4, the adhesive is an aqueous solution of carboxymethyl cellulose, wherein the concentration of carboxymethyl cellulose is 2-4 wt%.
[0015] The amount of adhesive added is 12-15 wt% of the dry mix.
[0016] Furthermore, in step S4, during sintering, the brick blank is heated to 250-300℃ at a rate of 2-3℃ / min, held for 15-30min, then heated to 800-950℃ at a rate of 1-2℃ / min, and then heated again to 1050-1150℃ at a rate of 0.5-1℃ / min, held for 30-45min, and then cooled to room temperature in the furnace to obtain a lightweight sintered brick prepared using waste felt carbon fiber.
[0017] Furthermore, a lightweight sintered brick prepared using waste felt carbon fiber is obtained by the above method.
[0018] Compared with the prior art, the beneficial effects of the present invention are:
[0019] This invention aims to improve the reuse of waste felt carbon fiber by modifying it as a raw material for sintered bricks. Since sintered bricks require high-temperature sintering at thousands of degrees Celsius during preparation, carbon fiber materials are often oxidized by air at this temperature, leading to performance degradation and even consumption. Therefore, to avoid oxidation loss of carbon fiber during sintering, this invention, after the old carbon fiber felt has been crushed and sheared, heats it to 450-500°C in a nitrogen atmosphere to remove surface resin. Then, it is cooled to about 300°C and placed in an air atmosphere to further remove resin residue. Afterward, it undergoes acid etching oxidation treatment to increase its surface hydroxyl content. Finally, it is mixed with KH550 and subjected to water... After the silica gel is formed, it is heated and methane gas is introduced to generate a silicon carbide layer on the surface of the carbon fiber. The silicon carbide layer can effectively protect the carbon fiber matrix, thereby preventing the carbon fiber from oxidizing at high temperatures. Furthermore, since carbon fiber is a brittle material, in order to avoid the decrease in bonding strength and mechanical strength of the sintered brick during the sintering process, this application also adds a boron mud component. Boron mud is an industrial solid waste generated during the production of borax and boric acid, which contains a large amount of amorphous substances. Adding it to the raw material can effectively improve the wettability of the carbon fiber, thereby better bonding the carbon fiber and the sintered brick and improving the flexural strength of the sintered brick. Detailed Implementation
[0020] Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of the present invention.
[0021] Example 1. A processing method for lightweight sintered bricks prepared using waste felt carbon fiber, comprising the following steps:
[0022] S1. After shearing and crushing the waste carbon fiber felt, a mixture of waste carbon fiber with a particle size of 15~20mm in each direction is obtained;
[0023] S2. The waste carbon fiber mixture is heated to 450℃ under a nitrogen atmosphere, held for 25 minutes, cooled to 300℃, air is introduced, held for 15 minutes, and then cooled to room temperature. The calcined waste carbon fiber mixture is added to clean water, ultrasonically treated to remove residual carbon powder on the surface, separated and dried, and then added again to a mixed acid of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1. The mixture is heated to 60℃, ultrasonically vibrated for 20 minutes, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber.
[0024] S3. By weight, 1 part of recycled carbon fiber was added to 5 parts of anhydrous ethanol, 0.1 part of KH550 was added, and after mixing evenly, 0.5 part of deionized water was added, followed by the addition of dilute hydrochloric acid. The pH of the mixture was adjusted to 3, and the mixture was ultrasonically vibrated for 12 hours. After drying to constant weight, the mixture was heated to 350℃ and held for 15 minutes under a nitrogen atmosphere. Then, the temperature was raised to 980℃, methane gas was introduced, and the mixture was held for 4 hours. Finally, the mixture was cooled to room temperature to obtain modified recycled carbon fiber.
[0025] S4. By weight, 20 parts of coal gangue were crushed and sieved to obtain coal gangue particles with a particle size of 1-3 mm; 20 parts of bentonite, 5 parts of red mud and 5 parts of boron mud were crushed and sieved to obtain bentonite particles, red mud particles and boron mud particles with a particle size of 0.05-0.1 mm. These were then mixed with 5 parts of modified recycled carbon fiber. A 2wt% carboxymethyl aqueous solution was added at 15% of the dry mixture mass to prepare a semi-wet blank. After the blank was shaped, it was aged in an environment of 20℃ and 85% relative humidity for 3 days. The blank was then sintered. During sintering, the blank was heated to 300℃ at 2℃ / min, held for 15 min, then heated to 850℃ at 2℃ / min, and then heated to 1100℃ again at a rate of 0.5℃ / min, held for 30 min, and then cooled to room temperature in the furnace to obtain a lightweight sintered brick made from waste felt carbon fiber.
[0026] Example 2. A processing method for lightweight sintered bricks prepared using waste felt carbon fiber, comprising the following steps:
[0027] Compared with Example 1, this example increases the amount of KH550 added in step S3;
[0028] S1. After shearing and crushing the waste carbon fiber felt, a mixture of waste carbon fiber with a particle size of 15~20mm in each direction is obtained;
[0029] S2. The waste carbon fiber mixture is heated to 450℃ under a nitrogen atmosphere, held for 25 minutes, cooled to 300℃, air is introduced, held for 15 minutes, and then cooled to room temperature. The calcined waste carbon fiber mixture is added to clean water, ultrasonically treated to remove residual carbon powder on the surface, separated and dried, and then added again to a mixed acid of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1. The mixture is heated to 60℃, ultrasonically vibrated for 20 minutes, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber.
[0030] S3. By weight, add 1 part of recycled carbon fiber to 5 parts of anhydrous ethanol, add 0.4 parts of KH550, mix well, add 0.5 parts of deionized water, continue to add dilute hydrochloric acid, adjust the pH of the mixture to 3, ultrasonically vibrate for 12 hours, dry to constant weight, heat to 350℃ and hold for 15 minutes under nitrogen atmosphere, heat to 980℃, introduce methane gas, hold for 4 hours, cool to room temperature, and obtain modified recycled carbon fiber.
[0031] S4. By weight, 20 parts of coal gangue were crushed and sieved to obtain coal gangue particles with a particle size of 1-3 mm; 20 parts of bentonite, 5 parts of red mud and 5 parts of boron mud were crushed and sieved to obtain bentonite particles, red mud particles and boron mud particles with a particle size of 0.05-0.1 mm. These were then mixed with 5 parts of modified recycled carbon fiber. A 2wt% carboxymethyl aqueous solution was added at 15% of the dry mixture mass to prepare a semi-wet blank. After the blank was shaped, it was aged in an environment of 20℃ and 85% relative humidity for 3 days. The blank was then sintered. During sintering, the blank was heated to 300℃ at 2℃ / min, held for 15 min, then heated to 850℃ at 2℃ / min, and then heated to 1100℃ again at a rate of 0.5℃ / min, held for 30 min, and then cooled to room temperature in the furnace to obtain a lightweight sintered brick made from waste felt carbon fiber.
[0032] Example 3. A processing method for lightweight sintered bricks prepared using waste felt carbon fiber, comprising the following steps:
[0033] Compared with Example 2, this example increases the amount of modified recycled carbon fiber added in step S4;
[0034] S1. After shearing and crushing the waste carbon fiber felt, a mixture of waste carbon fiber with a particle size of 15~20mm in each direction is obtained;
[0035] S2. The waste carbon fiber mixture is heated to 450℃ under a nitrogen atmosphere, held for 25 minutes, cooled to 300℃, air is introduced, held for 15 minutes, and then cooled to room temperature. The calcined waste carbon fiber mixture is added to clean water, ultrasonically treated to remove residual carbon powder on the surface, separated and dried, and then added again to a mixed acid of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1. The mixture is heated to 60℃, ultrasonically vibrated for 20 minutes, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber.
[0036] S3. By weight, add 1 part of recycled carbon fiber to 5 parts of anhydrous ethanol, add 0.4 parts of KH550, mix well, add 0.5 parts of deionized water, continue to add dilute hydrochloric acid, adjust the pH of the mixture to 3, ultrasonically vibrate for 12 hours, dry to constant weight, heat to 350℃ and hold for 15 minutes under nitrogen atmosphere, heat to 980℃, introduce methane gas, hold for 4 hours, cool to room temperature, and obtain modified recycled carbon fiber.
[0037] S4. By weight, 20 parts of coal gangue were crushed and sieved to obtain coal gangue particles with a particle size of 1-3 mm; 20 parts of bentonite, 5 parts of red mud and 5 parts of boron mud were crushed and sieved to obtain bentonite particles, red mud particles and boron mud particles with a particle size of 0.05-0.1 mm. These were then mixed with 15 parts of modified recycled carbon fiber. A 2wt% carboxymethyl aqueous solution was added at 15% of the dry mixture mass to prepare a semi-wet blank. After the blank was shaped, it was aged in an environment of 20℃ and 85% relative humidity for 3 days. The blank was then sintered. During sintering, the blank was heated to 300℃ at 2℃ / min, held for 15 min, then heated to 850℃ at 2℃ / min, and then heated to 1100℃ again at a rate of 0.5℃ / min, held for 30 min, and then cooled to room temperature in the furnace to obtain a lightweight sintered brick made from waste felt carbon fiber.
[0038] Example 4. A processing method for lightweight sintered bricks prepared using waste felt carbon fiber, comprising the following steps:
[0039] Compared with Example 3, this example increases the amount of boron mud added in step S4;
[0040] S1. After shearing and crushing the waste carbon fiber felt, a mixture of waste carbon fiber with a particle size of 15~20mm in each direction is obtained;
[0041] S2. The waste carbon fiber mixture is heated to 450℃ under a nitrogen atmosphere, held for 25 minutes, cooled to 300℃, air is introduced, held for 15 minutes, and then cooled to room temperature. The calcined waste carbon fiber mixture is added to clean water, ultrasonically treated to remove residual carbon powder on the surface, separated and dried, and then added again to a mixed acid of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1. The mixture is heated to 60℃, ultrasonically vibrated for 20 minutes, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber.
[0042] S3. By weight, add 1 part of recycled carbon fiber to 5 parts of anhydrous ethanol, add 0.4 parts of KH550, mix well, add 0.5 parts of deionized water, continue to add dilute hydrochloric acid, adjust the pH of the mixture to 3, ultrasonically vibrate for 12 hours, dry to constant weight, heat to 350℃ and hold for 15 minutes under nitrogen atmosphere, heat to 980℃, introduce methane gas, hold for 4 hours, cool to room temperature, and obtain modified recycled carbon fiber.
[0043] S4. By weight, 20 parts of coal gangue were crushed and sieved to obtain coal gangue particles with a particle size of 1-3 mm; 20 parts of bentonite, 5 parts of red mud and 10 parts of boron mud were crushed and sieved to obtain bentonite particles, red mud particles and boron mud particles with a particle size of 0.05-0.1 mm. These were then mixed with 15 parts of modified recycled carbon fiber. A 2wt% carboxymethyl aqueous solution was added at 15% of the dry mixture mass to prepare a semi-wet blank. After the blank was shaped, it was aged in an environment of 20℃ and 85% relative humidity for 3 days. The blank was then sintered. During sintering, the blank was heated to 300℃ at 2℃ / min, held for 15 min, then heated to 850℃ at 2℃ / min, and then heated to 1100℃ again at a rate of 0.5℃ / min, held for 30 min, and then cooled to room temperature in the furnace to obtain a lightweight sintered brick made from waste felt carbon fiber.
[0044] Comparative Example 1. A processing method for lightweight sintered bricks prepared using waste felt carbon fiber, comprising the following steps:
[0045] Compared with Example 1, no boron mud was added in this comparative example;
[0046] S1. After shearing and crushing the waste carbon fiber felt, a mixture of waste carbon fiber with a particle size of 15~20mm in each direction is obtained;
[0047] S2. The waste carbon fiber mixture is heated to 450℃ under a nitrogen atmosphere, held for 25 minutes, cooled to 300℃, air is introduced, held for 15 minutes, and then cooled to room temperature. The calcined waste carbon fiber mixture is added to clean water, ultrasonically treated to remove residual carbon powder on the surface, separated and dried, and then added again to a mixed acid of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1. The mixture is heated to 60℃, ultrasonically vibrated for 20 minutes, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber.
[0048] S3. By weight, 1 part of recycled carbon fiber was added to 5 parts of anhydrous ethanol, 0.1 part of KH550 was added, and after mixing evenly, 0.5 part of deionized water was added, followed by the addition of dilute hydrochloric acid. The pH of the mixture was adjusted to 3, and the mixture was ultrasonically vibrated for 12 hours. After drying to constant weight, the mixture was heated to 350℃ and held for 15 minutes under a nitrogen atmosphere. Then, the temperature was raised to 980℃, methane gas was introduced, and the mixture was held for 4 hours. Finally, the mixture was cooled to room temperature to obtain modified recycled carbon fiber.
[0049] S4. By weight, 20 parts of coal gangue were crushed and sieved to obtain coal gangue particles with a particle size of 1-3 mm; 20 parts of bentonite and 5 parts of red mud were crushed and sieved to obtain bentonite particles and red mud particles with a particle size of 0.05-0.1 mm. These were then mixed with 5 parts of modified recycled carbon fiber. A 2wt% carboxymethyl aqueous solution was added at 15% of the dry mixture mass to prepare a semi-wet blank. After the blank was shaped, it was aged in an environment of 20℃ and 85% relative humidity for 3 days. The blank was then sintered. During sintering, the blank was heated to 300℃ at 2℃ / min and held for 15 min. Then, it was heated to 850℃ at 2℃ / min and then heated to 1100℃ again at a rate of 0.5℃ / min and held for 30 min. Finally, it was cooled to room temperature in the furnace to obtain a lightweight sintered brick made from waste felt carbon fiber.
[0050] Comparative Example 2. A processing method for lightweight sintered bricks prepared using waste felt carbon fiber, comprising the following steps:
[0051] Compared with Example 1, this comparative example did not perform the original step S3.
[0052] S1. After shearing and crushing the waste carbon fiber felt, a mixture of waste carbon fiber with a particle size of 15~20mm in each direction is obtained;
[0053] S2. The waste carbon fiber mixture is heated to 450℃ under a nitrogen atmosphere, held for 25 minutes, cooled to 300℃, air is introduced, held for 15 minutes, and then cooled to room temperature. The calcined waste carbon fiber mixture is added to clean water, ultrasonically treated to remove residual carbon powder on the surface, separated and dried, and then added again to a mixed acid of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1. The mixture is heated to 60℃, ultrasonically vibrated for 20 minutes, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber.
[0054] S3. By weight, 20 parts of coal gangue were crushed and sieved to obtain coal gangue particles with a particle size of 1-3 mm; 20 parts of bentonite, 5 parts of red mud and 5 parts of boron mud were crushed and sieved to obtain bentonite particles, red mud particles and boron mud particles with a particle size of 0.05-0.1 mm. These were then mixed with 5 parts of recycled carbon fiber. A 2wt% carboxymethyl aqueous solution was added at 15% of the dry mixture mass to prepare a semi-wet blank. After the blank was shaped, it was aged in an environment of 20℃ and 85% relative humidity for 3 days. The blank was then sintered. During sintering, the blank was heated to 300℃ at 2℃ / min, held for 15 min, then heated to 850℃ at 2℃ / min, and then heated to 1100℃ again at a rate of 0.5℃ / min, held for 30 min, and then cooled to room temperature in the furnace to obtain a lightweight sintered brick made from waste felt carbon fiber.
[0055] Comparative Example 3. A processing method for lightweight sintered bricks prepared using waste felt carbon fiber, comprising the following steps:
[0056] Compared to Example 1, no carbon fiber was added in this comparative example;
[0057] By weight, 20 parts of coal gangue were crushed and sieved to obtain coal gangue particles with a particle size of 1-3 mm; 20 parts of bentonite, 5 parts of red mud and 5 parts of boron mud were crushed and sieved separately to obtain bentonite particles, red mud particles and boron mud particles with a particle size of 0.05-0.1 mm. These were then mixed with 5 parts of recycled carbon fiber. A 2wt% carboxymethyl aqueous solution was added at 15% of the dry mixture mass to prepare a semi-wet blank. After the blank was shaped, it was aged in an environment of 20℃ and 85% relative humidity for 3 days. The blank was then sintered. During sintering, the blank was heated to 300℃ at 2℃ / min, held for 15 min, then heated to 850℃ at 2℃ / min, and then heated again to 1100℃ at a rate of 0.5℃ / min, held for 30 min, and then cooled to room temperature in the furnace to obtain a lightweight sintered brick made from waste felt carbon fiber.
[0058] Testing: The flexural strength and splitting tensile strength of the lightweight sintered bricks prepared in Examples 1-4 and Comparative Examples 1-3 were tested according to GB / T 25993-2010; the test results are shown in the table below.
[0059]
[0060] Finally, it should be noted that the above descriptions are merely preferred embodiments of the present invention and are not intended to limit the present invention. Although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art can still modify the technical solutions described in the foregoing embodiments or make equivalent substitutions for some of the technical features. Any modifications, equivalent substitutions, improvements, etc., made within the spirit and principles of the present invention should be included within the protection scope of the present invention.
Claims
1. A processing technology for lightweight sintered bricks prepared using waste felt carbon fiber, characterized in that, Includes the following steps: S1. Waste carbon fiber felt is sheared and crushed to obtain a mixture of waste carbon fiber. The particle size length of the waste carbon fiber mixture in each direction is 5~25mm; S2. Under a nitrogen atmosphere, the waste carbon fiber mixture is heated to 450~500℃ and held for 25~40 min. Then, it is cooled to 300~350℃, air is introduced, and it is held for 10~15 min. After cooling to room temperature, the calcined waste carbon fiber mixture is added to clean water and ultrasonically treated to remove residual carbon powder on the surface. After separation and drying, it is added again to a mixture of concentrated sulfuric acid and concentrated nitric acid, heated to 60℃, ultrasonically vibrated for 20~40 min, centrifuged to separate the precipitate, washed until neutral, and dried to obtain recycled carbon fiber. The mixed acid is a mixed acid solution of concentrated sulfuric acid and concentrated nitric acid in a volume ratio of 3:1; S3. Add the recycled carbon fiber to anhydrous ethanol, add KH550, mix well, add deionized water, and continue to add dilute hydrochloric acid to adjust the pH of the mixture to 2.5~3.
5. After ultrasonic vibration reaction for 12 hours, dry to constant weight, heat to 350~400℃ under nitrogen atmosphere and hold for 10~15 minutes, then heat to 980~1050℃, introduce methane gas, hold for 1~4 hours, and cool to room temperature to obtain modified recycled carbon fiber. The composition, by weight, consists of 1 part recycled carbon fiber, 3-5 parts anhydrous ethanol, 0.1-0.4 parts KH550, and 0.5-1.5 parts deionized water. S4. After crushing and sieving coal gangue, bentonite, red mud and boron mud respectively, they are mixed with modified recycled carbon fiber to obtain dry mixture. After adding binder, a semi-wet blank is prepared. After blanking, it is placed in an environment of 20~25℃ and 85~95% relative humidity for 3~5 days. The brick blank is then sintered. During sintering, the brick blank is heated to 250~300℃ at 2~3℃ / min and held for 15~30min. Then, it is heated to 800~950℃ at 1~2℃ / min and then heated to 1050~1150℃ at 0.5~1℃ / min and held for 30~45min. After cooling to room temperature in the furnace, a lightweight sintered brick made from waste felt carbon fiber is obtained after sintering. Among them, the particle size of coal gangue after crushing is 1~3mm; the particle size of bentonite, red mud and boron mud after crushing is 0.05~0.1mm. By weight, the contents of each component are 20-35 parts coal gangue, 20-30 parts bentonite, 5-10 parts red mud, 5-10 parts boron mud and 5-15 parts modified recycled carbon fiber.
2. The processing technology for lightweight sintered bricks prepared using waste felt carbon fiber according to claim 1, characterized in that: In step S4, the adhesive is an aqueous solution of carboxymethyl cellulose, wherein the concentration of carboxymethyl cellulose is 2-4 wt%. The amount of adhesive added is 12-15 wt% of the dry mix.
3. A lightweight sintered brick prepared from waste felt carbon fiber using the processing technology described in any one of claims 1 to 2.
Citation Information
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