一种磷酸铁锂复合材料及其制备方法和应用

CN120841479BActive Publication Date: 2026-07-17TAIYUAN SAIYIN NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TAIYUAN SAIYIN NEW MATERIAL TECH CO LTD
Filing Date
2025-08-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Lithium iron phosphate (LFP) has low electronic conductivity and ion diffusion coefficient as a cathode material for lithium-ion batteries, resulting in high internal resistance and limiting its application in high-power devices. Furthermore, carbon coating causes LFP particles to agglomerate and grow, affecting cycle life.

Method used

Precursor powder was prepared by mixing lithium iron phosphate and a carbon source, and then subjected to high-temperature heat treatment at temperatures above 2800℃ to transform the carbon source into graphene. Hexagonal boron nitride was added to form COB covalent bonds with the graphene, establishing a stable three-dimensional conductive network and inhibiting the aggregation and growth of lithium iron phosphate particles.

Benefits of technology

It significantly improves the cycle life of lithium batteries by forming a stable three-dimensional conductive network, which suppresses the aggregation and growth of lithium iron phosphate particles and enhances the battery's lifespan.

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Abstract

本发明涉及锂电池正极材料技术领域,具体涉及一种磷酸铁锂复合材料及其制备方法和应用。包括以下步骤:将六方氮化硼加入到无水乙醇中超声分散,得到分散液;将磷酸铁锂和碳源加入到去离子水中搅拌,得到混合液;将分散液和混合液混合后,球磨、喷雾干燥,得到前驱体粉末;对前驱体粉末进行微波碳化处理和瞬态高能焦耳热场处理,得到磷酸铁锂复合材料;瞬态高能焦耳热场处理的温度为2800‑3200℃。本发明通过将磷酸铁锂和碳源混合制备成前驱体粉末,对其进行2800℃以上的高温热处理,使包覆的碳源表面在瞬时高温的条件下变为石墨烯,并通过加入六方氮化硼,使其与石墨烯发生高温协同效应,显著提高了锂电池的循环寿命。
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