乙二胺四亚甲基膦酸改性淀粉及其制备方法和应用

By grafting starch with ethylenediaminetetramethylenephosphonic acid to form a phosphonate ester bond and hydrogen bond network, the problem of low removal rate of modified starch in strongly acidic wastewater is solved, and the simultaneous and efficient removal of multiple metals is achieved, which is suitable for industrial wastewater treatment.

CN120865442BActive Publication Date: 2026-07-17HENAN JIE SURFACE NEW MATERIALS CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HENAN JIE SURFACE NEW MATERIALS CO LTD
Filing Date
2025-07-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing modified starch heavy metal scavengers perform well in neutral or alkaline environments, but their removal rate decreases in strongly acidic wastewater, and the pH value of the wastewater needs to be adjusted, which limits their application.

Method used

By grafting starch with ethylenediaminetetramethylenephosphonic acid under acid catalysis to form a phosphonate ester bond and hydrogen bond network, the hydrophilicity and active sites are enhanced, and a modified starch capable of efficiently removing heavy metals in a strongly acidic environment is prepared.

Benefits of technology

It achieves simultaneous and efficient removal of multiple metals in highly acidic wastewater without the need for pre-adjustment of wastewater pH, significantly improving the heavy metal removal rate.

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Abstract

本发明提供一种乙二胺四亚甲基膦酸改性淀粉及其制备方法和应用,步骤包括将淀粉分散溶液与酸催化后的乙二胺四亚甲基膦酸溶液进行混合,加入过硫酸铵,在氮气保护下进行恒温搅拌反应;反应液冷却后,加入乙醇沉淀接枝产物,得到乙二胺四亚甲基膦酸改性淀粉。该乙二胺四亚甲基膦酸改性淀粉通过将乙二胺四亚甲基膦酸与天然高分子淀粉进行接枝,形成高分子基重金属捕获剂,可在强酸性废水中实现多金属同步高效去除,无需预调废水的pH值。
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