一种高性能电池胶带用离型剂及其制备方法

By using a high-performance non-silicone release agent in liquid form for battery tapes, and employing a stepwise polymerization process and modification with nano-silica, the problems of insufficient electrolyte resistance and high-temperature stability of existing non-silicone release agents have been solved, enabling the production of highly reliable and environmentally friendly battery tapes.

CN120865770BActive Publication Date: 2026-07-17GUANGDONG CHUANGYANG NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUANGDONG CHUANGYANG NEW MATERIAL TECH CO LTD
Filing Date
2025-07-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing non-silicone release agents have shortcomings in electrolyte resistance and high-temperature stability, which makes the release force of the tape fluctuate easily when it is in contact with electrolyte or high-temperature environment for a long time, and the residual adhesion decreases, making it difficult to meet the needs of high-reliability battery production.

Method used

A high-performance non-silicone release agent for battery tapes in liquid form is produced by stepwise polymerization and modification with fluorinated monomers. Nano-silica with a surface modified by silane coupling agent is added to form a micro-nano roughness structure and a molecular-level repulsion layer, which improves the wear resistance and electrolyte resistance of the release layer. The production process is simplified by using a low-VOC composite solvent system.

Benefits of technology

Release force fluctuation is less than 5% under long-term storage or high-temperature environment, and residual adhesion retention rate is higher than 93%, which is significantly better than traditional technology, and meets environmental protection regulations. It also simplifies the production process and reduces energy consumption by 30%.

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Abstract

本发明公开了一种高性能电池胶带用非硅离型剂,包括:改性合成液4~6份,氨基树脂2~6份,功能性稀释剂4~9份,复合溶剂7~12份,纳米助剂0.1~0.5份;其中,改性合成液的制备方法包括:S1.将第一单体、含氟单体与丁酮‑乙醇混合溶剂混合均匀,通入氮气除氧后,升温至60~70℃,保持30~50分钟;S2.向步骤S1得到的混合液中加入第二单体、引发剂及链转移剂,然后于65~75℃下反应5~7小时;S3.将步骤S2得到的混合液升温至80~90℃,然后分三次加入第一单体和引发剂,每次反应1~1.5小时,得到所述改性合成液。本发明提供的高性能电池胶带用非硅离型剂,为液体形态,无需加热溶解,无颗粒污染,且在离型力稳定性、耐化学性及耐热性上优于现有技术。
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