一种化学气相沉积含氧硫化钴阴极的方法及应用

By depositing oxygen-containing cobalt sulfide on the surface of highly oriented pyrolytic graphite to form a polyhedral electrode, the stability and conductivity issues of cobalt-based catalysts were solved, and efficient generation of 1O2 for sterilization and pollutant degradation was achieved, demonstrating significant sterilization and degradation performance.

CN120903641BActive Publication Date: 2026-07-17QINGDAO UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
QINGDAO UNIV
Filing Date
2025-07-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing cobalt-based catalysts, such as CoS catalysts, suffer from poor stability and are easily oxidized, while CoO catalysts have poor conductivity and low catalytic efficiency, making it difficult to efficiently generate 1O2 for sterilization and pollutant degradation.

Method used

Oxygen-containing cobalt sulfide (CoSOX/HOPG) was deposited in one step on the surface of highly oriented pyrolytic graphite (HOPG) using chemical vapor deposition to form a polyhedral electrode. Combined with the CoSOX/HOPG electrode, 1O2 was efficiently generated under electrochemical conditions.

Benefits of technology

The CoSOX/HOPG electrode achieves efficient and stable generation of 1O2 in water treatment, rapidly inactivating bacteria and degrading dye pollutants. It has excellent bactericidal and degradation efficiency and is suitable for long-term use in complex environments.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN120903641B_ABST
    Figure CN120903641B_ABST
Patent Text Reader

Abstract

本发明涉及催化剂制备及性能检测与杀菌、污染物降解应用领域,具体公开了一种化学气相沉积含氧硫化钴阴极的方法,包括以下步骤:在管式炉中通入保护气与还原气的混合载气,程序升温至预定高温使CoCl2与S进行反应,在清洁导电衬底上进行气相沉积。反应结束后切断还原气,短暂引入空气使样品轻微氧化,直接得到CoSOX / 导电衬底的电化学催化反应阴极;CoSOX / 导电衬底克服了CoS稳定性差、易氧化、吸附能力弱与CoO催化能力弱、导电性差的缺陷,能够稳定高效的产生大量1O2来广谱性杀灭水体中的有害病原菌和有效降解罗丹明B、甲基橙和亚甲基蓝等有机污染物,该电催化杀菌体系具有极高的实际应用价值。
Need to check novelty before this filing date? Find Prior Art