一种高性能硅碳用沥青基多孔碳的制备方法

High-performance pitch-based porous carbon materials with a hierarchical pore structure were prepared through component separation, structural regulation, and surface modification processes. This solved the problems of uneven pore size distribution and insufficient mechanical strength in the existing technology, and improved the first-efficiency and cycle performance of lithium battery silicon-carbon materials.

CN120922872BActive Publication Date: 2026-07-17TANYAN TECHNOLOGY SERVICES (WUXI) CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TANYAN TECHNOLOGY SERVICES (WUXI) CO LTD
Filing Date
2025-08-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, pitch-based porous carbon materials cannot meet the first-efficiency and cycle performance requirements of lithium battery silicon-carbon materials, and the uneven pore size distribution leads to insufficient mechanical strength, which cannot effectively support the expansion and contraction of silicon particles.

Method used

Through an integrated process of component separation, structural regulation, and surface modification, the proportions of aromatics, resins, free carbon, oils, and waxes are precisely controlled. Combined with KOH activation and pitch self-activation, a hierarchical porous structure is formed, and functional groups such as carboxyl and sulfonic acid groups are introduced to improve the mechanical strength and electrochemical performance of the material.

Benefits of technology

The preparation of high-performance pitch-based porous carbon materials has been achieved, which have good pore size distribution, mechanical strength and electrochemical properties. They can effectively support the expansion and contraction of silicon particles and improve the first efficiency and cycle performance of lithium batteries.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提出一种高性能硅碳用沥青基多孔碳的制备方法,通过组分分离、结构调控、表面改姓的一体化工艺制备,烷烃溶剂溶解,过滤分离不溶物A,剩余物为油分和蜡质混合物B;将油分和蜡质混合物B溶于丙酮,冷冻使其中的蜡质结晶后,过滤分离蜡质晶体,滤液蒸馏回收丙酮后得到油分;将不溶物A与有机溶剂混合回流萃取,过滤分离得到游离碳,滤液为芳香族和树脂混合溶液C;采用柱色谱分离芳香族和树脂混合溶液C中的芳香族和树脂组分;将分离出的芳香族、树脂、游离碳、油分和蜡质按比例加热混合均匀得到调配好的沥青D;碳化活化处理再改性处理得到表面改性的沥青基多孔碳材料,可以满足电池在不同应用场景的应用需求。
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