一种高模量环氧树脂基结构胶材料及其制备方法

By optimizing the compounding of high-functionality epoxy resin, nano-reinforcing fillers, and toughening agents, the problem of insufficient modulus in traditional epoxy resin-based structural adhesives has been solved, resulting in structural adhesive materials that combine high modulus and toughness, suitable for aerospace and high-end automotive manufacturing.

CN120988622BActive Publication Date: 2026-07-17SUZHOU LUHU WEINING NEW MATERIAL TECHNOLOGY CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SUZHOU LUHU WEINING NEW MATERIAL TECHNOLOGY CO LTD
Filing Date
2025-08-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional epoxy resin-based structural adhesives are difficult to meet the high rigidity and deformation resistance requirements of aerospace and high-end automotive manufacturing in terms of modulus, and the addition of inorganic fillers may lead to a decrease in toughness and unstable bonding performance.

Method used

The high-functionality bisphenol F epoxy resin is compounded with alicyclic epoxy resin, combined with aromatic amine and acid anhydride curing agents, nano-reinforcing fillers such as surface-modified nano silica, nano calcium carbonate and modified multi-walled carbon nanotubes, toughening agents such as carboxyl-terminated butadiene nitrile rubber and EPDM rubber, and additives such as polyether-modified polysiloxane, etc., to improve modulus and toughness through uniform dispersion and chemical reaction.

Benefits of technology

The prepared high-modulus epoxy resin-based structural adhesive material maintains excellent bonding performance while achieving a tensile modulus of 8.3-9.6 GPa and a flexural modulus of 10.6-11.9 GPa, meeting the needs of high-end fields and possessing good impact resistance and stable modulus characteristics.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure SMS_1
    Figure SMS_1
Patent Text Reader

Abstract

本发明提供一种高模量环氧树脂基结构胶材料及其制备方法,涉及胶黏剂制备技术领域。环氧树脂基结构胶材料按照重量份,包括以下原料:40‑60份环氧树脂,15‑30份固化剂,5‑15份纳米增强填料,3‑8份增韧剂,2‑4份助剂和0.5‑2份促进剂。所述增韧剂为质量比1‑3:1的端羧基丁腈橡胶和三元乙丙橡胶,所述纳米增强填料为质量比1‑2:1:0.8‑1.2的表面修饰纳米二氧化硅,表面处理纳米碳酸钙和改性多壁碳纳米管。本发明的制备方法简单易行,各组分能够均匀分散,制备过程中无有害物质产生,得到的结构胶在具备优异粘结性能的同时,实现高模量特性,能够满足针对航空航天、汽车制造等高端领域对高强度、高模量结构胶粘剂的需求,具有良好的应用前景。
Need to check novelty before this filing date? Find Prior Art