具有快速离子传输通道的复合电解质膜及其制备方法

By using an inclusion complex of sulfobutyl-β-cyclodextrin and hydrophobic lithium-ion battery electrolyte solution in a polymer electrolyte membrane and applying an alternating electric field, an ordered composite electrolyte membrane is formed, which solves the problems of insufficient ionic conductivity and poor interfacial contact in polymer electrolyte membranes, and achieves efficient ion transport and improved battery safety.

CN121035328BActive Publication Date: 2026-07-17JIANGHAN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGHAN UNIVERSITY
Filing Date
2025-07-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polymer electrolyte membranes in lithium batteries suffer from insufficient ionic conductivity and poor interfacial contact, which limits battery performance. Furthermore, zero-dimensional nanofillers tend to agglomerate in the polymer matrix, hindering ion transport.

Method used

A composite electrolyte membrane with a fast ion transport channel was prepared by using an inclusion complex of sulfobutyl-β-cyclodextrin and hydrophobic lithium-ion battery electrolyte solution as a filler and forming an ordered arrangement in the polymer precursor solution by applying an alternating electric field.

Benefits of technology

It improves the ionic conductivity of lithium-ion batteries, forms continuous and rapid ion transport channels, suppresses lithium dendrite growth, and enhances battery safety and performance.

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Abstract

本发明提供一种具有快速离子传输通道的复合电解质膜的制备方法,包括:步骤1,将主体材料为磺丁基‑β‑环糊精、客体材料为疏水性锂离子电池电解质溶液用有机溶剂的包合物,作为填料添加到聚合物前驱体溶液中,混合均匀后倒入模具,在模具两端施加交流电场后再经紫外光固化,得到具有快速离子传输通道的复合物薄膜;步骤2,将所述复合物薄膜浸泡在锂离子电池电解质溶液中,将浸泡完成后的所述复合物薄膜真空干燥,得到具有快速离子传输通道的复合电解质膜。本发明将包合物作为填料添加到聚合物基体中,施加电场驱动填料粒子有序排列形成链状结构,有序排列的SBE‑β‑CD空腔包合的有机溶剂也形成了连续的快速离子传输通道,有效提高粒子传输效率。
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