一种快离子导体包覆多孔硅碳材料的制备方法

By depositing nano-silicon on porous carbon and coating it with lithium carbonate and titanium dioxide to form a fast ion conductor—titanium-doped lithium silicate—the problems of volume expansion and cycle stability of silicon-based anodes were solved, achieving high-capacity and stable lithium-ion battery performance.

CN121044567BActive Publication Date: 2026-07-17CHANGZHOU SIRUN NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHANGZHOU SIRUN NEW MATERIAL TECH CO LTD
Filing Date
2025-08-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional graphite anodes have limited theoretical capacity, while silicon-based anodes suffer from structural damage and poor cycle stability due to volume expansion during charging and discharging. Existing fast ion conductors coated with porous silicon-carbon materials also have insufficient cycle stability.

Method used

Using porous carbon as a carrier, nano-silicon is deposited through silicon source gas and oxidized to generate silicon oxide. Then, a novel surfactant is used to uniformly coat lithium carbonate and titanium dioxide to form a fast ion conductor - titanium-doped lithium silicate. Finally, a carbon layer is deposited through vapor phase to form a coating material, which improves conductivity and stability.

Benefits of technology

The charging specific capacity and cycle stability of the fast ion conductor-coated porous silicon-carbon material are improved. The ionic conductivity is enhanced by Ti ion doping, the carbon layer is deposited to reduce the interface resistance, reduce volume expansion, and enhance the cycle stability of the material.

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Abstract

本发明公开了一种快离子导体包覆多孔硅碳材料的制备方法,属于电池材料技术领域。所述快离子导体包覆多孔硅碳材料的制备方法包括以下步骤:将多孔碳放入回转炉中,通入载气和硅源气混合气体,煅烧,得到硅沉积材料;降温至100‑300℃,通入载气和氧气混合气体氧化,冷却得到多孔硅碳材料;将环己烷与表面活性剂超声分散,加入碳酸锂、二氧化钛搅拌均匀,加入多孔硅碳材料搅拌,蒸发溶剂后放入回转炉中,通入惰性气体,煅烧,冷却得到前驱体材料;通入载气和碳源气混合气体,煅烧,冷却得到快离子导体包覆的多孔硅碳材料。本发明制备的快离子导体包覆多孔硅碳材料具有良好的放电比容量和较高的循环稳定性。
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