一种可用于皮芯纺涤纶长效抗静电聚合物母粒的制备方法

By using an antistatic polymer masterbatch composed of hard and soft segments, the problems of poor antistatic performance and poor compatibility of core-spun polyester fibers in low-temperature and low-humidity environments have been solved, achieving stable conductivity and low-cost production.

CN121045759BActive Publication Date: 2026-07-17SHANGHAI BOMIAN IND CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANGHAI BOMIAN IND CO LTD
Filing Date
2025-09-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The existing core-spun polyester fibers have poor antistatic properties in low-temperature and low-humidity environments, and are prone to failure in subsequent processes. They also have poor compatibility, leading to short filaments and broken filaments during the spinning process, resulting in high production costs.

Method used

The antistatic polymer masterbatch is composed of hard and soft segments. The hard segments are made of aromatic polyesters and aliphatic diols, while the soft segments are made of aliphatic polyethers, polyaniline, protic acid, ionic liquids and fluorinated polymers. Block copolymers are formed through transesterification and polycondensation reactions to ensure that the masterbatch is stable and conductive in low temperature and low humidity environments, and the amount added is small.

Benefits of technology

It achieves stable antistatic effect in low temperature and low humidity environment, with no short filaments or broken filaments during spinning, reduces the amount of antistatic components added, improves the continuity of fiber production and the quality of finished products, and controls production costs.

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Abstract

本发明公开了一种可用于皮芯纺涤纶长效抗静电聚合物母粒的制备方法,涉及高分子材料制备技术领域。由硬段和软段组成,硬段包括以下组分:芳香族聚酯,所述芳香族聚酯由芳香族单体与脂肪族二元醇通过反应生成,其中芳香族单体为对苯二甲酸二甲酯,脂肪族二元醇为1,4‑丁二醇。本发明通过设置的硬段结构、软段结构以及聚苯胺、质子酸、离子液体、含氟聚合物、磺酸盐的配合,解决了涤纶母粒抗静电性能依赖环境湿度、后续工序易失效且与涤纶基体相容性差的问题,使得母粒在低温低湿环境下也能维持稳定抗静电效果,经加弹、印染等后续工序后性能不衰减,同时保障纺丝过程中无短丝、断丝,提升涤纶纤维生产的连续性与成品质量。
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Citation Information

Patent Citations

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  • Antistatic polyester fiber

    CN101555636A

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