基于CuO修饰梯度孔阳极的平板式SOFC及其制备方法和应用

By using CuO-modified gradient pore anodes and hydrothermal loading of copper oxide nanoparticles in a flat-plate SOFC, the problems of uneven methanol fuel diffusion and carbon deposition were solved, achieving efficient direct methanol power generation and stable operation.

CN121076192BActive Publication Date: 2026-07-17CHINA UNIV OF PETROLEUM (EAST CHINA)

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA UNIV OF PETROLEUM (EAST CHINA)
Filing Date
2025-08-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing flat-plate SOFCs suffer from uneven methanol diffusion and carbon buildup in direct methanol fuel power generation, resulting in low mass transfer efficiency and performance degradation, which traditional nickel-based anodes cannot effectively address.

Method used

By modifying the gradient pore anode with CuO, an anode layer with a gradient pore structure was prepared. Combined with in-situ loading of highly dispersed copper oxide nanoparticles by hydrothermal method, a directional mass transfer channel was constructed and the catalytic reforming effect was improved.

Benefits of technology

It enables direct power generation of methanol fuel on flat-plate SOFC, significantly improving mass transfer efficiency and anti-carbon deposition performance, and supporting stable operation under low water-to-carbon ratio.

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Abstract

本发明公开一种基于CuO修饰梯度孔阳极的平板式SOFC及其制备方法和应用,所述制备方法包括步骤:配制用于制备阳极层、电解质层、阻隔层、阴极层的浆料;采用流延成型工艺制备阳极层坯体,并利用相转化法制备阳极层,然后排胶;利用旋涂工艺在阳极层的上、下表面制备双面电解质层并烘干,然后进行烧结,得到梯度孔阳极支撑半电池;利用旋涂工艺在半电池的电解质层表面制备阻隔层并烧结;在阻隔层表面丝网印刷形成阴极层并烧结,得到梯度孔阳极支撑电池;利用硝酸铜水热溶液对梯度孔阳极支撑电池的阳极层进行水热处理,然后清洗烘干、烧结,得到CuO修饰梯度孔阳极的平板式SOFC。本发明所制备的平板式SOFC具有CuO修饰梯度孔阳极结构,实现甲醇燃料直接发电。
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