复合隔膜及其制备方法和电池

CN121123573BActive Publication Date: 2026-07-17JIANGSU ZENIO NEW ENERGY BATTERY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGSU ZENIO NEW ENERGY BATTERY TECH CO LTD
Filing Date
2025-10-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The ceramic coating of existing lithium-ion battery separators is fragile, lacks flexibility, has weak interfacial adhesion, and poor electrolyte affinity, which leads to battery shrinkage at high temperatures and poor electrolyte wettability.

Method used

The composite membrane design employs a layered structure. The first coating consists of silk fibroin with a low β-sheet structure, while the second coating consists of silk fibroin with a high β-sheet structure and modified ceramic particles. The interfacial bonding strength is enhanced through chemical bonds and hydrogen bonds, and the hydrophilicity of silk fibroin is used to improve electrolyte wettability.

Benefits of technology

It enhances the flexibility and thermal stability of the composite separator, improves electrolyte wettability and liquid retention, and enhances the mechanical strength and safety of the battery.

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Abstract

本申请涉及一种复合隔膜及其制备方法和电池,复合隔膜包括基膜、设置在基膜沿厚度方向上的至少一侧表面上的第一涂层、以及设置在第一涂层远离基膜的一侧表面上的第二涂层;第一涂层包括第一丝素蛋白,第二涂层包括第二丝素蛋白和陶瓷颗粒;第一丝素蛋白中β‑折叠结构的含量低于第二丝素蛋白中β‑折叠结构的含量;陶瓷颗粒包括改性陶瓷颗粒,改性陶瓷颗粒包括有机官能团,有机官能团包括氨基和 / 或环氧基。如此,通过第一涂层和第二涂层的组合,可有效提升复合隔膜的电解液浸润性及保液性能、柔韧性、耐刺穿性和热稳定性。
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